(2R)-(-)-Glycidyl tosylate

Modify Date: 2024-01-12 09:15:36

(2R)-(-)-Glycidyl tosylate Structure
(2R)-(-)-Glycidyl tosylate structure
 Common Name (2R)-(-)-Glycidyl tosylate
CAS Number 113826-06-5 Molecular Weight 228.265
Density 1.3±0.1 g/cm3 Boiling Point 370.5±15.0 °C at 760 mmHg
Molecular Formula C10H12O4S Melting Point 46-49 °C(lit.)
MSDS Chinese USA Flash Point 177.9±20.4 °C
Symbol GHS05 GHS08
GHS05, GHS08		 Signal Word Danger

 Names

Name (2R)-(-)-Glycidyl tosylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 370.5±15.0 °C at 760 mmHg
Melting Point 46-49 °C(lit.)
Molecular Formula C10H12O4S
Molecular Weight 228.265
Flash Point 177.9±20.4 °C
Exact Mass 228.045624
PSA 64.28000
LogP 1.35
Vapour Pressure 0.0±0.8 mmHg at 25°C
Index of Refraction 1.550
Water Solubility decomposes

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RR0510000
CHEMICAL NAME :
Oxiranemethanol, 4-methylbenzenesulfonate, (R)-
CAS REGISTRY NUMBER :
113826-06-5
BEILSTEIN REFERENCE NO. :
3592142
LAST UPDATED :
199612
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C10-H12-O4-S
MOLECULAR WEIGHT :
228.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :
Rodent - mouse
DOSE/DURATION :
100 mg/kg
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

 Safety Information

Symbol GHS05 GHS08
GHS05, GHS08
Signal Word Danger
Hazard Statements H318-H334-H350
Precautionary Statements P201-P261-P280-P305 + P351 + P338-P308 + P313
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes T:Toxic
Risk Phrases R45;R41;R43;R51/53;R68
Safety Phrases S61-S45-S36/37/39-S26-S53
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS RR0510000
Hazard Class 9.0
HS Code 29109000

 Synthetic Route

Tosyl chloride structure

Tosyl chloride

CAS#:98-59-9

(±)-Glycidol structure

(±)-Glycidol

CAS#:57044-25-4

~92%

(2R)-(-)-Glycidyl tosylate Structure

(2R)-(-)-Glycid...

CAS#:113826-06-5

Literature: Weinstabl, Harald; Gaich, Tanja; Mulzer, Johann Organic Letters, 2012 , vol. 14, # 11 p. 2834 - 2837
(2S)-3-Chlorpropan-1,2-diol structure

(2S)-3-Chlorpro...

CAS#:60827-45-4

dichloroethane structure

dichloroethane

CAS#:107-06-2

Tosyl chloride structure

Tosyl chloride

CAS#:98-59-9

~69%

(2R)-(-)-Glycidyl tosylate Structure

(2R)-(-)-Glycid...

CAS#:113826-06-5

Literature: Daiso Co., LTd. Patent: US5965753 A1, 1999 ;
Allyl alcohol structure

Allyl alcohol

CAS#:107-18-6

Tosyl chloride structure

Tosyl chloride

CAS#:98-59-9

~%

(S)-Glycidyl tosylate structure

(S)-Glycidyl to...

CAS#:70987-78-9

(2R)-(-)-Glycidyl tosylate Structure

(2R)-(-)-Glycid...

CAS#:113826-06-5

Literature: Journal of Organic Chemistry, , vol. 51, # 19 p. 3710 - 3712

 Customs

HS Code 29109000

 Articles1

More Articles
Henry, N. et al.

Tetrahedron Lett. 45 , 1465, (2004)

 Synonyms

2-Oxiranemethanol, 4-methylbenzenesulfonate, (2R)-
2-Oxiranemethanol, 4-methylbenzenesulfonate, (2S)-
(2R)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(2R)-(−)-Glycidyl tosylate
[(2R)-oxiran-2-yl]methyl 4-methylbenzenesulfonate
(2R)-(-)-Glycidyl p-Toluenesulfonate
(R)-(−)-Glycidyl p-toluenesulfonate
(2R)-2-Oxiranylmethyl 4-methylbenzenesulfonate
MFCD00010834
(R)-(-)-Glycidyltosylate
(-)-Glycidyl tosylate
Oxiranemethanol, 4-methylbenzenesulfonate, (R)-
(2S)-2-Oxiranylmethyl 4-methylbenzenesulfonate
(R)-(−)-Oxirane-2-methanol p-toluenesulfonate
(2R)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(R)-oxiran-2-ylmethyl 4-methylbenzenesulfonate
(R)-(−)-Glycidyl tosylate
EINECS 205-970-0
(2S)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(R)-(−)-Oxirane-2-methanol p-toluenesulfonate salt
(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(2R)-(-)-Glycidyl tosylate
T3OTJ B1OSWR D1 &&S Form
(2S)-Glycidyl tosylate
(R)-Glycidyl tosylate
p-Toluenesulfonic Acid (2R)-(-)-Glycidyl Ester
(S)-Glycidyl tosylate
(R)-(-)-Glycidyl tosylate
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