allyl-chloro-palladium structure
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Common Name | allyl-chloro-palladium | ||
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CAS Number | 12012-95-2 | Molecular Weight | 365.890 | |
Density | N/A | Boiling Point | N/A | |
Molecular Formula | C6H10Cl2Pd2 | Melting Point | 120°C (dec.) | |
MSDS | Chinese USA | Flash Point | N/A | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | Allylpalladium chloride dimer |
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Synonym | More Synonyms |
Melting Point | 120°C (dec.) |
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Molecular Formula | C6H10Cl2Pd2 |
Molecular Weight | 365.890 |
Exact Mass | 363.822937 |
LogP | 3.65900 |
Vapour Pressure | 8480mmHg at 25°C |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Faceshields;Gloves |
Hazard Codes | Xi:Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | 26-36 |
RIDADR | UN 3278 |
WGK Germany | 3 |
RTECS | RT3510000 |
Packaging Group | I |
Hazard Class | 6.1(a) |
HS Code | 28439090 |
Precursor 0 | |
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DownStream 1 | |
HS Code | 28439090 |
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Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.
J. Am. Chem. Soc. 125 , 3718, (2003) This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a varie... |
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The first applications of carbene ligands in cross-couplings of alkyl electrophiles: sonogashira reactions of unactivated alkyl bromides and iodides.
J. Am. Chem. Soc. 125 , 13642, (2003) A Pd/N-heterocyclic carbene-based catalyst achieves the Sonogashira coupling of an array of functionalized, beta-hydrogen-containing alkyl bromides and iodides under mild conditions. By furnishing the... |
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Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.
J. Am. Chem. Soc. 123 , 4366, (2001)
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chloropalladium(1+),prop-1-ene |
MFCD00044874 |
Bis(allylchloropalladium) |
[PdCl(allyl)]2 |
EINECS 234-579-8 |
Bis(allyl)dichlorodipalladium |
Diallyldichlorodipalladium |
Allylpalladium(II) Chloride Dimer |
[PdCl(C3H5)]2 |
Bis(allyl)dichloropalladium |
Di-μ-chlorobis[(η-allyl)palladium(II)] |
Allylchloropalladium dimer |