2-Methyl-5-nitrobenzenesulfonyl chloride

Modify Date: 2024-01-09 11:11:03

2-Methyl-5-nitrobenzenesulfonyl chloride Structure
2-Methyl-5-nitrobenzenesulfonyl chloride structure
 Common Name 2-Methyl-5-nitrobenzenesulfonyl chloride
CAS Number 121-02-8 Molecular Weight 235.64500
Density 1.528 g/cm3 Boiling Point 135-137°C/0.7mm
Molecular Formula C7H6ClNO4S Melting Point 43 °C
MSDS Chinese USA Flash Point 135-137°C/0.7mm
Symbol GHS05
GHS05		 Signal Word Danger

 Names

Name 2-Methyl-5-nitrobenzenesulfonyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.528 g/cm3
Boiling Point 135-137°C/0.7mm
Melting Point 43 °C
Molecular Formula C7H6ClNO4S
Molecular Weight 235.64500
Flash Point 135-137°C/0.7mm
Exact Mass 234.97100
PSA 88.34000
LogP 3.43470
Vapour Pressure 2.57E-05mmHg at 25°C
Index of Refraction 1.576

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XT8000000
CHEMICAL NAME :
o-Toluenesulfonyl chloride, 5-nitro-
CAS REGISTRY NUMBER :
121-02-8
BEILSTEIN REFERENCE NO. :
2697079
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C7-H6-Cl-N-O4-S
MOLECULAR WEIGHT :
235.65
WISWESSER LINE NOTATION :
WSGR B1 ENW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1072,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1072,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7470 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1072,1986

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive;
Risk Phrases R14;R29;R34
Safety Phrases S22-S26-S30-S45-S8-S36/37/39
RIDADR 3261
RTECS XT8000000
Packaging Group II
Hazard Class 8
HS Code 2904909090

 Synthetic Route

4-Nitrotoluene structure

4-Nitrotoluene

CAS#:99-99-0

~98%

2-Methyl-5-nitrobenzenesulfonyl chloride Structure

2-Methyl-5-nitr...

CAS#:121-02-8

Literature: Tagiev; Kazaz; Anyl Russian Journal of Applied Chemistry, 2012 , vol. 85, # 10 p. 1581 - 1585 Zh. Prikl. Khim. (S.-Peterburg, Russ. Fed.), 2012 , vol. 85, # 10 p. 1648 - 1652,5
Carbon disulphide structure

Carbon disulphide

CAS#:75-15-0

Aluminium chloride structure

Aluminium chloride

CAS#:7446-70-0

2-methyl-5-nitro-benzenesulfonyl fluoride structure

2-methyl-5-nitr...

CAS#:453-53-2

~%

2-Methyl-5-nitrobenzenesulfonyl chloride Structure

2-Methyl-5-nitr...

CAS#:121-02-8

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. <2> 117, p. 21

 Customs

HS Code 2904909090
Summary HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

 Synonyms

EINECS 204-444-8
2-Methyl-5-Nitrobenzene-1-Sulfonyl Chloride
5-Nitro-o-toluenesulfonyl Chloride
4-nitrotoluene-2-sulfochloride
Benzenesulfonyl chloride,2-methyl-5-nitro
2-Methyl-5-nitrobenzenesulfonylchloride
5-nitro-2-methyl-phenylsulfonyl chloride
MFCD00051695
4-Nitrotoluene-2-sulphonyl chloride
2-Methyl-5-nitrobenzenesulfonyl Chloride
2-methyl-5-nitro-benzene-sulfonyl chloride
4-Nitrotoluen-2-sulfochlorid
2-methyl-5-nitro-benzenesulphonyl chloride
o-Toluenesulfonyl chloride,5-nitro
sulfonyl chloride
5-nitro-2-methylbenzenesulfonylchloride
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