2-(Tributylstannyl)-1,3-thiazole

Acute toxicity, Oral (Category 3)
Skin irritation (Category 2)
Eye irritation (Category 2)
Specific target organ toxicity - repeated exposure (Category 1)
Acute aquatic toxicity (Category 1)
According to European Directive 67/548/EEC as amended.
Toxic if swallowed. Toxic: danger of serious damage to health by prolonged exposure through inhalation and if
swallowed. Harmful in contact with skin. Irritating to eyes and skin. Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Label elements
Pictogram
Signal wordDanger
Hazard statement(s)
H301Toxic if swallowed.
H312Harmful in contact with skin.
H315Causes skin irritation.
H319Causes serious eye irritation.
H372Causes damage to organs through prolonged or repeated exposure.
H400Very toxic to aquatic life.
Precautionary statement(s)
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing.
P301 + P310IF SWALLOWED: Immediately call a POISON CENTER or
doctor/physician.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P314Get medical advice/attention if you feel unwell.
Hazard symbol(s)
TToxic
NDangerous for the environment
R-phrase(s)
R21Harmful in contact with skin.
R25Toxic if swallowed.
R36/38Irritating to eyes and skin.
R48/23/25Toxic: danger of serious damage to health by prolonged exposure through
inhalation and if swallowed.
R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
S-phrase(s)
S35This material and its container must be disposed of in a safe way.
S36/37/39Wear suitable protective clothing, gloves and eye/face protection.
S45In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
S60This material and its container must be disposed of as hazardous waste.
S61Avoid release to the environment. Refer to special instructions/ Safety data
sheets.
Other hazards - none

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Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Formula: C15H29NSSn
Molecular Weight: 374,17 g/mol
CAS-No.EC-No.Index-No.ClassificationConcentration
2-Tributylstannylthiazole
121359-48-6-050-008-00-3Acute Tox. 4; Acute Tox. 3;-
Skin Irrit. 2; Eye Irrit. 2; STOT
RE 1; Aquatic Acute 1; H301,
H312, H315, H319, H372,
H400
T, N, R21 - R25 - R36/38 -
R48/23/25 - R50/53
For the full text of the H-Statements mentioned in this Section, see Section 16.

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Section4. FIRST AID MEASURES
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing give artificial respiration Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

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Section5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.

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Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.
Evacuate personnel to safe areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed
containers for disposal.

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Section7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Normal measures for preventive fire protection.
Conditions for safe storage
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are
opened must be carefully resealed and kept upright to prevent leakage.

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Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with
multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to
engineering controls. If the respirator is the sole means of protection, use a full-face supplied air
respirator. Use respirators and components tested and approved under appropriate government
standards such as NIOSH (US) or CEN (EU).
Hand protection
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Handle with gloves.
Eye protection
Face shield and safety glasses
Skin and body protection
Choose body protection according to the amount and concentration of the dangerous substance at the
work place.
Hygiene measures
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the
product.

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Section9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Formliquid
Colourcolourless
Safety data
pHno data available
Melting pointno data available
Boiling point307 - 309 °C - lit.
Flash point> 110 °C - closed cup
Ignition temperatureno data available
Lower explosion limitno data available
Upper explosion limitno data available
Density1,19 g/cm3 at 25 °C
Water solubilityno data available

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Section10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
Strong oxidizing agentsStrong oxidizing agents, Strong mineral acids, Bases
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx),
Sulphur oxides, Tin/tin oxides

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Section11. TOXICOLOGICAL INFORMATION
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard
no data available
Potential health effects
InhalationToxic if inhaled. May cause respiratory tract irritation.
IngestionToxic if swallowed.
Skin
Harmful if absorbed through skin. Causes skin irritation.
EyesCauses eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.
Additional Information
RTECS: no data available

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Section12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

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Section13. DISPOSAL CONSIDERATIONS
Product
Observe all federal, state, and local environmental regulations. Contact a licensed professional waste
disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn
in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

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Section14. TRANSPORT INFORMATION
ADR/RID
UN-Number: 2788 Class: 6.1Packing group: II
Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole)
IMDG
UN-Number: 2788 Class: 6.1Packing group: IIEMS-No: F-A, S-A
Proper shipping name: ORGANOTIN COMPOUND, LIQUID, N.O.S. (2-Tributylstannylthiazole)
Marine pollutant: Marine pollutant
IATA
UN-Number: 2788 Class: 6.1Packing group: II
Proper shipping name: Organotin compound, liquid, n.o.s. (2-Tributylstannylthiazole)

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Section15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

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Section16. OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Acute Tox.Acute toxicity
Aquatic AcuteAcute aquatic toxicity
Eye Irrit.Eye irritation
H301Toxic if swallowed.
H312Harmful in contact with skin.
H315Causes skin irritation.
H319Causes serious eye irritation.
H372Causes damage to organs through prolonged or repeated exposure.
H400Very toxic to aquatic life.
Skin Irrit.Skin irritation
STOT RESpecific target organ toxicity - repeated exposure
NDangerous for the environment
TToxic
R21Harmful in contact with skin.
R25Toxic if swallowed.
R36/38Irritating to eyes and skin.
R48/23/25Toxic: danger of serious damage to health by prolonged exposure through inhalation
and if swallowed.
R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Further information
Copyright 2010 Co. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and is
applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee
of the properties of the product. Co., shall not be held liable for any damage resulting from
handling or from contact with the above product. See reverse side of invoice or packing slip for additional
terms and conditions of sale.