Ethyl trifluoropyruvate

Modify Date: 2024-01-03 19:08:27

Ethyl trifluoropyruvate structure	Common Name	Ethyl trifluoropyruvate
	CAS Number	13081-18-0	Molecular Weight	170.087
	Density	1.3±0.1 g/cm3	Boiling Point	88.1±40.0 °C at 760 mmHg
	Molecular Formula	C₅H₅F₃O₃	Melting Point	N/A
	MSDS	Chinese USA	Flash Point	8.1±22.2 °C
	Symbol	GHS02, GHS07	Signal Word	Warning

Name	Ethyl trifluoropyruvate
Synonym	More Synonyms

Density	1.3±0.1 g/cm3
Boiling Point	88.1±40.0 °C at 760 mmHg
Molecular Formula	C₅H₅F₃O₃
Molecular Weight	170.087
Flash Point	8.1±22.2 °C
Exact Mass	170.019073
PSA	43.37000
LogP	1.57
Vapour Pressure	62.0±0.2 mmHg at 25°C
Index of Refraction	1.349
Storage condition	Refrigerator

Ethyl trifluoropyruvate MSDS(Chinese)

Symbol	GHS02, GHS07
Signal Word	Warning
Hazard Statements	H226-H302-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes	Xi:Irritant;
Risk Phrases	R10;R36/37/38
Safety Phrases	S26-S37/39-S16
RIDADR	UN 3272 3/PG 3
WGK Germany	3
Packaging Group	III
Hazard Class	3
HS Code	2918300090

ethyl 2-ethoxy-...

CAS#:10186-66-0

~84%

Ethyl trifluoro...

CAS#:13081-18-0

Literature: E. I. Du Pont de Nemours and Company Patent: US4357282 A1, 1982 ;

ethyl 2-ethoxy-...

CAS#:10186-66-0

~82%

fluoroethane

CAS#:353-36-6

Ethyl trifluoro...

CAS#:13081-18-0

Literature: England, David C. Journal of Organic Chemistry, 1984 , vol. 49, # 21 p. 4007 - 4008

Bromotrifluorom...

CAS#:75-63-8

Diethyloxalate

CAS#:95-92-1

~37%

Ethyl trifluoro...

CAS#:13081-18-0

Literature: Francese, C.; Tordeux, M.; Wakselman, C. Tetrahedron Letters, 1988 , vol. 29, # 9 p. 1029 - 1030

Ethanol

CAS#:64-17-5

3,3,3-trifluoro...

CAS#:10321-14-9

Ethyl trifluoro...

CAS#:13081-18-0

Literature: Gazzetta Chimica Italiana, , vol. 98, p. 265 - 276

Hexafluoropropy...

CAS#:428-59-1

Ethanol

CAS#:64-17-5

Ethyl trifluoro...

CAS#:13081-18-0

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 19, # 8 p. 1563 - 1564 Zhurnal Organicheskoi Khimii, , vol. 19, # 8 p. 1761 - 1762

Precursor 6
CAS#:10186-66-0 ethyl 2-ethoxy-... CAS#:75-63-8 Bromotrifluorom... CAS#:95-92-1 Diethyloxalate CAS#:64-17-5 Ethanol
CAS#:10321-14-9 3,3,3-trifluoro... CAS#:428-59-1 Hexafluoropropy...
DownStream 9
CAS#:431-72-1 Trifluoropyruvi... CAS#:58457-64-0 2-HYDROXY-3-(TR... CAS#:126535-90-8 ethyl 2-[tert-b... CAS#:126535-87-3 ethyl 2-benzoyl...
CAS#:126535-92-0 ETHYL 2-[BENZYL... CAS#:1817-49-8 Benzenemethanol... CAS#:217195-91-0 ethyl 2-hydroxy... CAS#:910656-46-1 (2R)-2-(5-amino...
CAS#:94726-00-8 Ethyl 3,3,3-tri...

HS Code	2918300090
Summary	2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Organocatalytic enantioselective Friedel–Crafts alkylation of simple phenols with trifluoropyruvate. Zhao JL, et al.

Tetrahedron Lett. 49(9) , 1476-1479, (2008)

Novel Enantiocomplementary C₂-Symmetric Chiral Bis (imidazoline) Ligands: Highly Enantioselective Friedel–Crafts Alkylation of Indoles with Ethyl 3, 3, 3-Trifluoropyruvate. Nakamura S, et al.

Adv. Synth. Catal. 350(10) , 1443-1448, (2008)

Synthesis of N-Heteroaryl (trifluoromethyl) hydroxyalkanoic Acid Esters by Highly Efficient Solid Acid-Catalyzed Hydroxyalkylation of Indoles and Pyrroles with Activated Trifluoromethyl Ketones. Abid M and Török B.

Adv. Synth. Catal. 347(14) , 1797-1803, (2005)

Ethyl 3,3,3-trifluoro-2-oxopropanoate

Ethyl trifluoropyruvate

Propanoic acid, 3,3,3-trifluoro-2-oxo-, ethyl ester

Trifluoropyruvic acid ethyl ester

Ethyl 2-oxo-3,3,3-trifluoropropanoate

Ethyl 3,3,3-trifluoropyruvate

MFCD00114935

FXFFVVO2

Ethyltrifluoropyruvate