Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate

Modify Date: 2024-01-10 15:48:39

Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure
Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate structure
Common Name Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate
CAS Number 13148-05-5 Molecular Weight 390.41100
Density 1.18g/cm3 Boiling Point 544ºC at 760mmHg
Molecular Formula C24H23O3P Melting Point 101-106ºC
MSDS Chinese USA Flash Point 295.8ºC

 Names

Name ethyl 3-oxo-4-(triphenylphosphoranylidene)butyrate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.18g/cm3
Boiling Point 544ºC at 760mmHg
Melting Point 101-106ºC
Molecular Formula C24H23O3P
Molecular Weight 390.41100
Flash Point 295.8ºC
Exact Mass 390.13800
PSA 53.18000
LogP 3.30500
Vapour Pressure 6.78E-12mmHg at 25°C
Index of Refraction 1.596
Storage condition -20°C Freezer
Stability Moisture Sensitive

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Safety Phrases 24/25
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2931900090

 Synthetic Route

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Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: Chemische Berichte, , vol. 96, p. 2943 - 2949

~34%

Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: UNIVERSITE JOSEPH FOURIER; CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE Patent: US2010/298422 A1, 2010 ; Location in patent: Page/Page column 25 ;

~83%

Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: Sun, King Mo; Dawe, Robert D.; Fraser-Reid, Bert Carbohydrate Research, 1987 , vol. 171, p. 35 - 48

~60%

Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: Stergiou, Anastasios; Bariotaki, Anna; Kalaitzakis, Dimitris; Smonou, Ioulia Journal of Organic Chemistry, 2013 , vol. 78, # 14 p. 7268 - 7273

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Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: Australian Journal of Chemistry, , vol. 41, # 10 p. 1591 - 1600

~%

Ethyl 3-oxo-4-(triphenylphosphoranylidene)butanoate Structure

Ethyl 3-oxo-4-(...

CAS#:13148-05-5

Literature: Carbohydrate Research, , vol. 171, p. 35 - 48

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles2

More Articles

Tetrahedron Lett. 34 , 4837, (1993)

Synthesis , 453, (1992)

 Synonyms

ethyl 3-oxo-4-(triphenyl-λ<sup>5</sup>-phosphanylidene)butanoate
Ethyl 3-oxo-4-(triphenylphosphoranylidene)butyrate
MFCD00192162