Bicyclo[3.2.0]hept-2-en-6-one

Modify Date: 2024-01-02 18:56:24

Bicyclo[3.2.0]hept-2-en-6-one structure	Common Name	Bicyclo[3.2.0]hept-2-en-6-one
	CAS Number	13173-09-6	Molecular Weight	108.138
	Density	1.1±0.1 g/cm3	Boiling Point	186.6±9.0 °C at 760 mmHg
	Molecular Formula	C₇H₈O	Melting Point	N/A
	MSDS	USA	Flash Point	66.3±13.7 °C
	Symbol	GHS05, GHS07	Signal Word	Danger

Name	(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one
Synonym	More Synonyms

Density	1.1±0.1 g/cm3
Boiling Point	186.6±9.0 °C at 760 mmHg
Molecular Formula	C₇H₈O
Molecular Weight	108.138
Flash Point	66.3±13.7 °C
Exact Mass	108.057518
PSA	17.07000
LogP	0.45
Vapour Pressure	0.7±0.4 mmHg at 25°C
Index of Refraction	1.546

Bicyclo[3.2.0]hept-2-en-6-one MSDS(Chinese)

Symbol	GHS05, GHS07
Signal Word	Danger
Hazard Statements	H302-H315-H318-H335
Precautionary Statements	P261-P280-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xn:Harmful;
Risk Phrases	R22;R37/38;R41
Safety Phrases	S26-S39
RIDADR	UN1224
WGK Germany	3
Packaging Group	III
Hazard Class	3
HS Code	2914299000

7,7-dichlorobic...

CAS#:5307-99-3

~67%

Bicyclo[3.2.0]h...

CAS#:13173-09-6

Literature: Fairlamb, Ian J.S.; Dickinson, Julia M.; O'Connor, Rachael; Higson, Seamus; Grieveson, Lynsey; Marin, Veronica Bioorganic and Medicinal Chemistry, 2002 , vol. 10, # 8 p. 2641 - 2656

2,2-dichloroethenone

CAS#:4591-28-0

Cyclopentadiene

CAS#:542-92-7

~82%

Bicyclo[3.2.0]h...

CAS#:13173-09-6

Literature: Howard, Colin C.; Newton, Roger F.; Reynolds, Derek P.; Wardsworth, Alan H.; Kelly, David R.; Roberts, Stanley M. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 852 - 857

Cyclopentadiene

CAS#:542-92-7

Bicyclo[3.2.0]h...

CAS#:13173-09-6

Literature: Journal of Organic Chemistry, , vol. 65, # 17 p. 5396 - 5402

(rac)-6-endo-bi...

CAS#:13259-28-4

~90%

Bicyclo[3.2.0]h...

CAS#:13173-09-6

Literature: Dawson, Michael J.; Lawrence, Gordon C.; Lilley, Gerald; Todd, Martin; Noble, David; at al. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , p. 2119 - 2125

Dichloroacetyl ...

CAS#:79-36-7

Cyclopentadiene

CAS#:542-92-7

Bicyclo[3.2.0]h...

CAS#:13173-09-6

Literature: Tetrahedron, , vol. 27, p. 615 - 633

Precursor 4
CAS#:5307-99-3 7,7-dichlorobic... CAS#:4591-28-0 2,2-dichloroethenone CAS#:542-92-7 Cyclopentadiene CAS#:79-36-7 Dichloroacetyl ...
DownStream 7
CAS#:1521-45-5 7-bicyclo[3.2.0... CAS#:34638-25-0 3,3a,6,6a-tetra... CAS#:128946-78-1 (1R 5S)-3-OXABI... CAS#:103618-27-5 (+)-(1S,5R)-3-o...
CAS#:73057-70-2 Spiro[bicyclo[3... CAS#:74877-21-7 2-(4-oxocyclope... CAS#:77189-14-1 1H-Cyclopenta[c...

HS Code	2914299000
Summary	2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Asymmetric Baeyer-Villiger oxidation with Co (Salen) and H2O2 in water: striking supramolecular micelles effect on catalysis. Bianchini G, et al.

Green Chem. 11(10) , 1517-1520, (2009)

Synthesis and Characterization of New Chalcone Derivatives from cis-Bicyclo [3.2. 0] hept-2-en-6-one Ceylan M and Findik E.

Synth. Commun. 39(6) , 1049-54, (2009)

Preparative scale Baeyer-Villiger biooxidation at high concentration using recombinant Escherichia coli and in situ substrate feeding and product removal process.

Nat. Protoc. 3(3) , 546-54, (2008)

An efficient biocatalytic process based on the use of adsorbent resin (in situ substrate feeding and product removal) makes experiments at high substrate concentration possible by overcoming limitatio...

MFCD00066201

Bicyclo[3.2.0]hept-2-en-6-one

bicyclo[3.2.0]hept-3-en-7-one