2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]

Modify Date: 2024-01-03 19:27:32

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure
2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] structure
 Common Name 2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]
CAS Number 132098-54-5 Molecular Weight 266.379
Density 1.1±0.1 g/cm3 Boiling Point 328.8±25.0 °C at 760 mmHg
Molecular Formula C15H26N2O2 Melting Point 51-53ºC(lit.)
MSDS USA Flash Point 124.8±15.7 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name (4S)-4-tert-butyl-2-[[(4S)-4-tert-butyl-4,5-dihydro-1,3-oxazol-2-yl]methyl]-4,5-dihydro-1,3-oxazole
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 328.8±25.0 °C at 760 mmHg
Melting Point 51-53ºC(lit.)
Molecular Formula C15H26N2O2
Molecular Weight 266.379
Flash Point 124.8±15.7 °C
Exact Mass 266.199432
PSA 43.18000
LogP 1.65
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.528
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26
RIDADR NONH for all modes of transport
WGK Germany 3.0

 Synthetic Route

(S)-tert-Leucinol structure

(S)-tert-Leucinol

CAS#:112245-13-3

Diethyl propanediimidate dihydrochloride structure

Diethyl propane...

CAS#:10344-69-1

~69%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Denmark, Scott E.; Nakajima, Noriyuki; Stiff, Cory M.; Nicaise, Olivier J.-C.; Kranz, Michael Advanced Synthesis and Catalysis, 2008 , vol. 350, # 7-8 p. 1023 - 1045
N1,N3-bis((S)-1-hydroxy-3,3-dimethylbutan-2-yl)malonamide structure

N1,N3-bis((S)-1...

CAS#:133463-95-3

~42%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

N/A structure

N/A

CAS#:133464-00-3

Literature: Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240
N/A structure

N/A

CAS#:133464-00-3

~%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240
(S)-tert-Leucinol structure

(S)-tert-Leucinol

CAS#:112245-13-3

~%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240
N1,N3-bis((S)-1-hydroxy-3,3-dimethylbutan-2-yl)malonamide structure

N1,N3-bis((S)-1...

CAS#:133463-95-3

~%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Helvetica Chimica Acta, , vol. 74, # 1 p. 232 - 240
malonodiimidic acid diethyl ester dihydrochloride structure

malonodiimidic ...

CAS#:878766-81-5

(S)-tert-Leucinol structure

(S)-tert-Leucinol

CAS#:112245-13-3

~%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Chemistry - An Asian Journal, , vol. 6, # 1 p. 78 - 82
(S)-tert-Leucinol structure

(S)-tert-Leucinol

CAS#:112245-13-3

Diethyl malonate structure

Diethyl malonate

CAS#:105-53-3

~%

2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline] Structure

2,2'-Methyleneb...

CAS#:132098-54-5

Literature: Tetrahedron Letters, , vol. 31, # 42 p. 6005 - 6008

 Articles3

More Articles
Gant, T.G. Meyers, A.I.

Tetrahedron 50 , 2297, (1994)

Pfaltz, A.

Acc. Chem. Res. 26 , 339, (1993)

Bolm, C.

Angew. Chem. Int. Ed. Engl. 30 , 542, (1991)

 Synonyms

Oxazole, 2,2'-methylenebis[4-(1,1-dimethylethyl)-4,5-dihydro-, (4S,4'S)-
MFCD00192290
(S,S)-2,2'-Methylenebis(4-tert-butyl-2-oxazoline)
2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]
(4S,4'S)-2,2'-Methylenebis[4-(2-methyl-2-propanyl)-4,5-dihydro-1,3-oxazole]
tBuBOX
hms1526d16
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Chemsrc provides CAS#:132098-54-5 MSDS, density, melting point, boiling point, structure, etc. Its name is 2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]>> amp version: 2,2'-Methylenebis[(4S)-4-tert-butyl-2-oxazoline]

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