PENTAFLUOROPHENYL CHLOROTHIONOFORMATE

Modify Date: 2024-01-05 11:12:02

PENTAFLUOROPHENYL CHLOROTHIONOFORMATE Structure
PENTAFLUOROPHENYL CHLOROTHIONOFORMATE structure
Common Name PENTAFLUOROPHENYL CHLOROTHIONOFORMATE
CAS Number 135192-53-9 Molecular Weight 262.58400
Density 1.635 g/mL at 25ºC(lit.) Boiling Point 98-102ºC50 mm Hg(lit.)
Molecular Formula C7ClF5OS Melting Point N/A
MSDS Chinese USA Flash Point 189 °F
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name O-(2,3,4,5,6-pentafluorophenyl) chloromethanethioate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.635 g/mL at 25ºC(lit.)
Boiling Point 98-102ºC50 mm Hg(lit.)
Molecular Formula C7ClF5OS
Molecular Weight 262.58400
Flash Point 189 °F
Exact Mass 261.92800
PSA 41.32000
LogP 3.28460
Vapour Pressure 1.03mmHg at 25°C
Index of Refraction n20/D 1.481(lit.)

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C
Risk Phrases 34
Safety Phrases 26-27-36/37/39-45
RIDADR UN 3265 8/PG 2
HS Code 2930909090

 Synthetic Route

~90%

PENTAFLUOROPHENYL CHLOROTHIONOFORMATE Structure

PENTAFLUOROPHEN...

CAS#:135192-53-9

Literature: Barton, Derek H. R.; Blundell, Paul; Dorchak, Joseph; Jang, Doo Ok; Jaszberenyi, Joseph Cs. Tetrahedron, 1991 , vol. 47, # 43 p. 8969 - 8984

~3%

PENTAFLUOROPHENYL CHLOROTHIONOFORMATE Structure

PENTAFLUOROPHEN...

CAS#:135192-53-9

Literature: Chiefari, John; Mayadunne, Roshan T.A.; Moad, Catherine L.; Moad, Graeme; Rizzardo, Ezio; Postma, Almar; Skidmore, Melissa A.; Thang, San H. Macromolecules, 2003 , vol. 36, # 7 p. 2273 - 2283

 Customs

HS Code 2930909090
Summary 2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles3

More Articles
Regioselective synthesis of beta-N1- and beta-N3-alloxazine nucleosides

Org. Lett. 2(2) , 227-30, (2000)

[structures: see text] A regio- and stereoselective glycosylation of ribose tetraester with persilylated alloxazine to give either beta-N1 or beta-N3 nucleosides is described. The N3 product is potent...

Tuning the acceptors in catalyzed cyclizations initiated by allenes. Silylstannylation/cyclization of allene-aldehydes for synthesis of polyalkylated indolizidines including 223A congeners.

J. Org. Chem. 69(26) , 9151-8, (2004)

Starting from succinamide and 1,2-heptadiene-4-ol, a racemic allene-aldehyde substrate, 20, suitable for R(3)SiSnR'(3)-mediated cyclization was synthesized in six steps and in 21% yield. Stereoselecti...

The invention of radical reactions. Part XXI. Simple methods for the radical deoxygenation of primary alcohols. Barton DHR, et al.

Tetrahedron 47(43) , 8969-94, (1991)

 Synonyms

Pentafluorophenyl Chlorothionoformate
Pentafluorophenyl Thionochloroformate
Chlorothioformic Acid O-Pentafluorophenyl Ester
pentafluorophenoxythiocarbonyl chloride
pentafluorophenyloxythiocarbonyl chloride
O-Perfluorophenyl Chlorothioformate
O-pentafluorophenyl chlorothionoformate
O-pentafluorophenyl chlorothioformate
P1267
MFCD00075405
O-perfluorophenyl carbonochloridethioate
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