(1R,2R)-Trost ligand
Modify Date: 2024-01-04 18:47:14
(1R,2R)-Trost ligand structure
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Common Name | (1R,2R)-Trost ligand | ||
|---|---|---|---|---|
| CAS Number | 138517-61-0 | Molecular Weight | 690.748 | |
| Density | N/A | Boiling Point | 817.0±65.0 °C at 760 mmHg | |
| Molecular Formula | C44H40N2O2P2 | Melting Point | 134-136ºC | |
| MSDS | Chinese USA | Flash Point | 447.9±34.3 °C | |
| Name | (R,R)-DACH-phenyl Trost ligand |
|---|---|
| Synonym | More Synonyms |
| Boiling Point | 817.0±65.0 °C at 760 mmHg |
|---|---|
| Melting Point | 134-136ºC |
| Molecular Formula | C44H40N2O2P2 |
| Molecular Weight | 690.748 |
| Flash Point | 447.9±34.3 °C |
| Exact Mass | 690.256531 |
| PSA | 85.38000 |
| LogP | 9.87 |
| Vapour Pressure | 0.0±2.9 mmHg at 25°C |
| Hazard Codes | Xi:Irritant; |
|---|---|
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-36/37/39 |
| RIDADR | NONH for all modes of transport |
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~92%
(1R,2R)-Trost ligand CAS#:138517-61-0 |
| Literature: Trost, Barry M.; Van Vranken, David L.; Bingel, Carsten Journal of the American Chemical Society, 1992 , vol. 114, # 24 p. 9327 - 9343 |
| Precursor 2 | |
|---|---|
| DownStream 0 | |
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Asymmetric Transition Metal-Catalyzed Allylic Alkylations.
Chem. Rev. 96 , 395, (1996)
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Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.
Chem. Rev. 103 , 2921, (2003)
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Trost, B.M. et al.
J. Am. Chem. Soc. 124 , 11616, (2004)
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| Trost ligand |
| (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl) |
| (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) |
| (R,R)-DACH-Phenyl Trost Ligand |
| MFCD01631273 |
| Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)- |
| (1R,2R)-(+)-N,N'-Bis(2-diphenylphosphinobenzoyl)-1,2-diaminocyclohexane |
| N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide] |
| 2-Diphenylphosphanyl-N-[(1R,2R)-2- [(2-diphenylphosphanylbenzoyl) amino]cyclohexyl]benzamide |
| 2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylbenzoyl)amino]cyclohexyl]benzamide |