Ethynyl 4-methylphenyl sulfone structure
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Common Name | Ethynyl 4-methylphenyl sulfone | ||
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CAS Number | 13894-21-8 | Molecular Weight | 180.224 | |
Density | 1.2±0.1 g/cm3 | Boiling Point | 297.9±33.0 °C at 760 mmHg | |
Molecular Formula | C9H8O2S | Melting Point | 73-74ºC(lit.) | |
MSDS | Chinese USA | Flash Point | 155.6±18.1 °C | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | Ethynyl p-Tolyl Sulfone |
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Synonym | More Synonyms |
Density | 1.2±0.1 g/cm3 |
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Boiling Point | 297.9±33.0 °C at 760 mmHg |
Melting Point | 73-74ºC(lit.) |
Molecular Formula | C9H8O2S |
Molecular Weight | 180.224 |
Flash Point | 155.6±18.1 °C |
Exact Mass | 180.024506 |
PSA | 42.52000 |
LogP | 2.43 |
Vapour Pressure | 0.0±0.6 mmHg at 25°C |
Index of Refraction | 1.553 |
Water Solubility | organic solvents: soluble(lit.) |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xi: Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2904100000 |
HS Code | 2904100000 |
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Summary | 2904100000 derivatives containing only sulpho groups, their salts and ethyl esters。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0% |
Tosvinyl and besvinyl as protecting groups of imides, azinones, nucleosides, sultams, and lactams. Catalytic conjugate additions to tosylacetylene.
J. Org. Chem. 79(18) , 8826-34, (2014) The use of the 2-(4-methylphenylsulfonyl)ethenyl (tosvinyl, Tsv) group for the protection of the NH group of a series of imides, azinones (including AZT), inosines, and cyclic sulfonamides has been ex... |
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Efficient and practical method for synthesizing optically active indan-2-ols by the Ti(O-i-Pr)(4)/2 i-PrMgCl-mediated metalative Reppe reaction.
J. Org. Chem. 68(12) , 4980-3, (2003) An efficient and practical synthesis of optically active indan-2-ols 1 has been developed starting from readily accessible optically active 4-siloxy-1,6-alkadiynes 2 and ethynyl p-tolyl sulfone, where... |
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A Simplified Method for the Preparation of Ethynyl P-Tolyl Sulfone and Ethynyl Phenyl Sulfone. Chen Z and Trudell ML.
Synth. Commun. 24(21) , 3149-55, (1994)
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Tosylacetylene |
Benzene, 1-(ethynylsulfonyl)-4-methyl- |
p-Toluenesulfonylacetylene |
Ethynyl 4-methylphenyl sulfone |
1-ethynylsulfonyl-4-methylbenzene |
MFCD00191647 |
p-Toluenesulfonylacetylene Tosylacetylene |
1-(Ethynylsulfonyl)-4-methylbenzene |