(Acetylacetonato)dicarbonyliridium (I) structure
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Common Name | (Acetylacetonato)dicarbonyliridium (I) | ||
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CAS Number | 14023-80-4 | Molecular Weight | 347.34500 | |
Density | N/A | Boiling Point | 100ºC (0.05 torr) | |
Molecular Formula | C7H7IrO4 | Melting Point | >145℃ | |
MSDS | N/A | Flash Point | N/A |
Use of (Acetylacetonato)dicarbonyliridium (I)(Acetylacetonato)dicarbonyliridium(I) is a catalyst for isomerization and anti-Markovnikov arylation of olefins. It is also a reactant for oxidative addition of perfluoroalkyl iodides, synthesis of iridium heterocycles, scaffolding of iridium complexes, metal carbonyl cluster synthesis, and mixed-bridged bimetallic d8 complex synthesis. |
Name | (acetylacetonato)dicarbonyliridium(i) |
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Synonym | More Synonyms |
Boiling Point | 100ºC (0.05 torr) |
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Melting Point | >145℃ |
Molecular Formula | C7H7IrO4 |
Molecular Weight | 347.34500 |
Exact Mass | 347.99700 |
PSA | 26.30000 |
LogP | 0.54410 |
Stability | store cold |
Section 1: Product Identification Chemical Name:Dicarbonylacetylacetonato iridium (I), 98% CAS Registry Number:14023-80-4 Formula:Ir(CO)2(CH3COCHCOCH3) EINECS Number:none Chemical Family:metal carbonyl complexes Synonym:Dicarbonyl(2.4-pentanedionato)iridium (I)
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14023-80-4100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Inhalation, skin contact Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store cold in a tightly sealed container. Keep away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:copper brown xtl. Molecular Weight:347.35 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and iridium compounds. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xn: Harmful; |
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Risk Phrases | R20/21/22 |
Safety Phrases | 22-26-36 |
RIDADR | UN3466 |
WGK Germany | 3 |
Packaging Group | III |
Hazard Class | 6.1 |
Dicarbonyl(2,4-pentanedionato)iridium |
2,4-Pentanedionatodicarbonyl iridium |
MFCD00049135 |
IRIDIUM I DICARBONYL PENTANEDIONATE |
Dicarbonyl(2,4-pentanedionato)iridium(I) |
(Acetylacetonato)dicarbonyliridium(I) |