1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE

Modify Date: 2024-01-08 12:02:40

1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE Structure
1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE structure
Common Name 1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE
CAS Number 141556-42-5 Molecular Weight 304.42900
Density N/A Boiling Point 442.706ºC at 760 mmHg
Molecular Formula C21H24N2 Melting Point 140ºC
MSDS Chinese USA Flash Point 199.09ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name 1,3-Dimesitylimidazol-2-ylidene
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 442.706ºC at 760 mmHg
Melting Point 140ºC
Molecular Formula C21H24N2
Molecular Weight 304.42900
Flash Point 199.09ºC
Exact Mass 304.19400
PSA 6.48000
LogP 5.17470
Appearance of Characters Powder | white to off-white
Vapour Pressure 0mmHg at 25°C
Storage condition ?20°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H228-H315-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes Xi: Irritant;
Risk Phrases R10
Safety Phrases S26
RIDADR UN 1325 4.1/PG 3
HS Code 2933290090

 Synthetic Route

~84%

1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE Structure

1,3-DIMESITYL-1...

CAS#:141556-42-5

Literature: Arduengo III, Anthony J.; Rasika Dias; Harlow, Richard L.; Kline, Michael Journal of the American Chemical Society, 1992 , vol. 114, # 14 p. 5530 - 5534

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1,3-DIMESITYL-1H-IMIDAZOL-3-IUM-2-IDE Structure

1,3-DIMESITYL-1...

CAS#:141556-42-5

Literature: Angewandte Chemie - International Edition, , vol. 52, # 31 p. 8045 - 8049 Angew. Chem., , vol. 125, # 31 p. 8203 - 8207

 Precursor & DownStream

Precursor  2

DownStream  0

 Customs

HS Code 2933290090
Summary 2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles1

More Articles
Normal-to-Abnormal NHC Rearrangement of Al(III) , Ga(III) , and In(III) Trialkyl Complexes: Scope, Mechanism, Reactivity Studies, and H2 Activation.

Chemistry 21 , 17959-72, (2015)

The present contribution reports experimental and theoretical mechanistic investigations on a normal-to-abnormal (C2-to-C4-bonded) NHC rearrangement processes occurring with bulky group 13 metal NHC a...

 Synonyms

1,3-DiMesityliMidazol-2-ylidene
1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene
MFCD09265338
1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-yli
1,3-bis(2,4,6-trimethylphenyl)-2H-imidazol-1-ium-2-ide
1,3-Dimesityl-1H-imidazol-3-ium-2-ide
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