(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one

Modify Date: 2024-01-09 16:16:04

(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one Structure
(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one structure
Common Name (3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one
CAS Number 149625-80-9 Molecular Weight 328.476
Density 1.0±0.1 g/cm3 Boiling Point 410.3±45.0 °C at 760 mmHg
Molecular Formula C16H28O5Si Melting Point -52ºC(lit.)
MSDS N/A Flash Point 167.8±24.3 °C

 Names

Name (3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 410.3±45.0 °C at 760 mmHg
Melting Point -52ºC(lit.)
Molecular Formula C16H28O5Si
Molecular Weight 328.476
Flash Point 167.8±24.3 °C
Exact Mass 328.170593
PSA 53.99000
LogP 3.59
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.462

 Synthetic Route

~98%

(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one Structure

(3aR,4R,7aR)-4-...

CAS#:149625-80-9

Literature: Park, Tae Kyo; Kim, In Jong; Hu, Shuanghua; Bilodeau, Mark T.; Randolph, John T.; Kwon, Ohyun; Danishefsky, Samuel J. Journal of the American Chemical Society, 1996 , vol. 118, # 46 p. 11488 - 11500

~%

(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one Structure

(3aR,4R,7aR)-4-...

CAS#:149625-80-9

Literature: Kwon, Ohyun; Danishefsky, Samuel J. Journal of the American Chemical Society, 1998 , vol. 120, # 7 p. 1588 - 1599

~%

(3aR,4R,7aR)-4-[tri(propan-2-yl)silyloxymethyl]-4,7a-dihydro-3aH-[1,3]dioxolo[4,5-c]pyran-2-one Structure

(3aR,4R,7aR)-4-...

CAS#:149625-80-9

Literature: Kwon, Ohyun; Danishefsky, Samuel J. Journal of the American Chemical Society, 1998 , vol. 120, # 7 p. 1588 - 1599

 Synonyms

6-O-triisopropyl-3,4-cyclocarbonate galactal
D-arabino-Hex-5-enitol, 2,6-anhydro-3,4-O-carbonyl-5-deoxy-1-O-[tris(1-methylethyl)silyl]-
2,6-Anhydro-5-deoxy-3,4-O-(oxomethylene)-1-O-(triisopropylsilyl)-D-arabino-hex-5-enitol
1,5-anhydro-3,4-O-carbonyl-2-deoxy-6-O-triisopropylsilyl-D-lyxo-hex-1-enitol
MFCD01321242