2-chlorophenyl phosphorodichloridate

Modify Date: 2024-01-19 18:49:42

2-chlorophenyl phosphorodichloridate Structure
2-chlorophenyl phosphorodichloridate structure
Common Name 2-chlorophenyl phosphorodichloridate
CAS Number 15074-54-1 Molecular Weight 245.42800
Density 1.491 g/mL at 25 °C(lit.) Boiling Point 135-137 °C12 mm Hg(lit.)
Molecular Formula C6H4Cl3O2P Melting Point N/A
MSDS Chinese USA Flash Point 221 °F
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name 2-Chlorophenylphosphoryl Dichloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.491 g/mL at 25 °C(lit.)
Boiling Point 135-137 °C12 mm Hg(lit.)
Molecular Formula C6H4Cl3O2P
Molecular Weight 245.42800
Flash Point 221 °F
Exact Mass 243.90100
PSA 36.11000
LogP 4.30450
Vapour Pressure 0.0113mmHg at 25°C
Index of Refraction n20/D 1.538(lit.)
Storage condition 2-8°C

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 8
HS Code 2931900090

 Synthetic Route

~51%

2-chlorophenyl phosphorodichloridate Structure

2-chlorophenyl ...

CAS#:15074-54-1

Literature: Malik, Payal; Chakraborty, Debashis; Ramkumar, Venkatachalam Polyhedron, 2010 , vol. 29, # 10 p. 2142 - 2148

~91%

2-chlorophenyl phosphorodichloridate Structure

2-chlorophenyl ...

CAS#:15074-54-1

Literature: Rathore, M.; Kabra, A.; Rani, P.; Narang, C. K.; Mathur, N. K. Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1993 , vol. 32, # 10 p. 1066 - 1067

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles3

More Articles

J. Chem. Soc. Perkin Trans. I , 2291, (1993)

Dealkylation of nucleoside arylmethyl 2-chlorophenyl phosphates: the 2, 4-dinitrobenzyl protecting group. Christadoulou C and Reese CB.

Tetrahedron Lett. 24(9) , 951-54, (1983)

A new approach to the synthesis of oligonucleotides and their phosphorothioate analogues in solution. Reese CB and Song Q.

Bioorg. Med. Chem. Lett. 7(21) , 2787-92, (1997)

 Synonyms

2-Chlorophenyl phosphorodichloridate
MFCD00009704
2-Chlorophenyl Phosphorodichloridate [Phosphorylating Agent]
EINECS 239-129-4
1-chloro-2-dichlorophosphoryloxybenzene
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