n-propyldichlorophosphine

Synonym:Dichloropropylphosphine, Phosphine, dichloropropyl-

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound15573-31-6100%no datano data

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Section 3: Hazards Identification
Material has a pungent odor. Inhalation of vapor may cause coughing, headache, and pulmonary edema. Very
Emergency Overview:
corrosive to eyes, skin, nose, and mucous membranes.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of vapor.
Eye Contact:Causes burns to the eyes.
Causes mild to severe irritation of the skin. Hydrochloric acid hydrolysis product is a corrosive liquid or vapor.
Skin Contact:
Inhalation:Corrosive Inhalation may cause spasms, coughing, chemical pneumonitis and pulmonary edema.
Ingestion:Corrosive to mouth throat and stomach. May cause dizziness, nausea, vomiting, pain and stomach upset.
Material has a pungent odor. Inhalation of vapor may cause chemical pneumonitis and pulmonary edema.
Acute Health Affects:
Contact of liquid or vapor with eyes and skin causes burns.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this material is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIn a fire material may emit toxic organic fumes, carbon monoxide, carbon dioxide, and phosphorous pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
Spill and Leak Procedures:Spillage in areas not adequately ventilated will require an evacuation of site. Emergency response teams will
require self-contained breathing apparatus.

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SECTION 7: Handling and Storage
Store in a cool, dry, well-ventilated area. Keep containers tightly sealed. Transfer material under an inert
Handling and Storage:
atmosphere of nitrogen or argon.

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SECTION 8: Exposure Controls and Personal Protection
Always wear safety glasses. If pouring or transferring this substance wear a face shield for additional
Eye Protection:
protection.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material has a pungent odor. Always handle material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material has a pungent odor. Always handle material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:colorless liq.
Molecular Weight:144.97
Melting Point:no data
Boiling Point:133°C
Vapor Pressure:no data
Specific Gravity:1.118
Odor:sharp acidic odor
Solubility in Water:Reacts vigorously with water

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SECTION 10: Stability and Reactivity
Stability:air sensitive, moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with air or moisture
Incompatibility:Water, air, oxidizing agents, active metals, oxygen and sulfur
Decomposition Products:carbon dioxide, carbon monoxide, phosphorus oxide, hydrogen chloride, and organic fumes

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SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Corrosive liquids, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):I
UN ID Number (CFR):UN# 1760
Shipping Name (IATA):Corrosive liquid, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):I
UN ID Number (IATA):UN# 1760

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SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A