(2-sulfanylidene-1,3-oxathiolan-5-yl)methyl 2-methylprop-2-enoate

Modify Date: 2024-02-29 10:25:02

(2-sulfanylidene-1,3-oxathiolan-5-yl)methyl 2-methylprop-2-enoate Structure
(2-sulfanylidene-1,3-oxathiolan-5-yl)methyl 2-methylprop-2-enoate structure
Common Name (2-sulfanylidene-1,3-oxathiolan-5-yl)methyl 2-methylprop-2-enoate
CAS Number 161196-23-2 Molecular Weight 218.29300
Density 1.3g/cm3 Boiling Point 317.7ºC at 760 mmHg
Molecular Formula C8H10O3S2 Melting Point N/A
MSDS N/A Flash Point 145.9ºC

 Names

Name (2-sulfanylidene-1,3-oxathiolan-5-yl)methyl 2-methylprop-2-enoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3g/cm3
Boiling Point 317.7ºC at 760 mmHg
Molecular Formula C8H10O3S2
Molecular Weight 218.29300
Flash Point 145.9ºC
Exact Mass 218.00700
PSA 92.92000
LogP 1.52260
Vapour Pressure 0.000379mmHg at 25°C
Index of Refraction 1.575

 MSDS


Section I.Chemical Product and Company Identification
Chemical Name 5-(Methacryloyloxy)methyl-1,3-oxathiolane-2-thione
Portland OR
2-Propenoic acid, 2-methyl-, (2-thioxo-1,3-
Synonym
oxathiolan-5-yl)methyl ester (9CI)
C8H10O3S2
Chemical Formula
CAS Number161196-23-2

Section II.Composition and Information on Ingredients
Chemical NameCAS Number Percent (%)TLV/PELToxicology Data
5-(Methacryloyloxy)methyl-1,3-oxathiolane-2-thione161196-23-2Min. 97.0 Not available.Not available.
(GC)

Section III. Hazards Identification
Harmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death.
Acute Health Effects
This material produces an irritating stench. Do not inhale and always use under a fume hood. Inhalation can result in
inflammation of the respiratory system, headaches, nausea, and vomiting. Always cover all exposed skin with an
impermeable layer and use proper eye protection. A OSHA/MSHA approved dust and vapor respirator is required when
working with this material.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Chronic Health EffectsCARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.

Section IV.First Aid Measures
Eye ContactCheck for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention.
Skin ContactIn case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing
before reuse. Thoroughly clean shoes before reuse. Get medical attention.
InhalationIf the victim is not breathing, perform mouth-to-mouth resuscitation. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, oxygen can be administered. Seek medical attention if respiration problems do not
improve.
IngestionINDUCE VOMITING by sticking finger in throat. Lower the head so that the vomit will not reenter the mouth and throat.
Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the
toxic material was ingested; the absence of such signs, however, is not conclusive.

Section V.Fire and Explosion Data
Auto-IgnitionNot available.
FlammabilityMay be combustible at high temperature.
Flash PointsFlammable LimitsNot available.
Not available.
Combustion ProductsThese products are toxic carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...).
Fire Hazards
Not available.
Risks of explosion of the product in presence of mechanical impact: Not available.
Explosion Hazards
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
and Instructions
Consult with local fire authorities before attempting large scale fire-fighting operations.
Continued on Next Page
5-(Methacryloyloxy)methyl-1,3-oxathiolane-2-thione

Section VI.Accidental Release Measures
Spill CleanupStench material. Harmful material.
Use a shovel to put the material into a convenient waste disposal container. Consult federal, state, and/or local
Instructions
authorities for assistance on disposal.

Section VII. Handling and Storage
STENCH. HARMFUL. REFRIGERATE. Keep away from heat. Mechanical exhaust required. When not in use, tightly
Handling and Storage
seal the container and store in a dry, cool place. Avoid excessive heat and light. Do not breathe dust.
Information
Always store away from incompatible compounds such as oxidizing agents.

Section VIII. Exposure Controls/Personal Protection
Engineering ControlsUse process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal ProtectionSplash goggles. Lab coat. Dust respirator. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
a specialist BEFORE handling this product. Be sure to use a MSHA/NIOSH approved respirator or equivalent.
Exposure LimitsNot available.

Section IX. Physical and Chemical Properties
Solid. (Yellow Crystalline Powder.)Solubility
Physical state @ 20°CNot available.
Not available.
Specific Gravity
Molecular Weight218.29Partition CoefficientNot available.
Boiling Point
Not available.Vapor PressureNot applicable.
Melting PointNot available.Vapor DensityNot available.
Refractive IndexNot available.VolatilityNot available.
Critical TemperatureNot available.OdorStench.
ViscosityNot available.TasteNot available.

Section X.Stability and Reactivity Data
Stability
This material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of InstabilityAvoid excessive heat and light.
IncompatibilitiesReactive with oxidizing agents.

Section XI. Toxicological Information
Not available.
RTECS Number
Eye Contact. Ingestion. Inhalation.
Routes of Exposure
Toxicity DataNot available.
Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure to this compound is not known to aggravate existing medical conditions.
Acute Toxic EffectsHarmful if ingested or inhaled. Minimize exposure to this material. Severe overexposure can result in injury or death.
This material produces an irritating stench. Do not inhale and always use under a fume hood. Inhalation can result in
inflammation of the respiratory system, headaches, nausea, and vomiting. Always cover all exposed skin with an
impermeable layer and use proper eye protection. A OSHA/MSHA approved dust and vapor respirator is required when
working with this material.
Follow safe industrial hygiene practices and always wear proper protective equipment when handling this compound.
Continued on Next Page
5-(Methacryloyloxy)methyl-1,3-oxathiolane-2-thione

Section XII.Ecological Information
EcotoxicityNot available.
Not available.
Environmental Fate

Section XIII. Disposal Considerations
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material with a
Waste Disposal
combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. Observe all
federal, state and local regulations when disposing of the substance.

Section XIV. Transport Information
DOT ClassificationDOT Class 9: Miscellaneous hazardous material.
PIN Number
Proper Shipping Name
Aviation regulated solid, n.o.s.
Packing Group (PG)Not available.
DOT Pictograms

Section XV. Other Regulatory Information and Pictograms
TSCA Chemical InventoryThis product is NOT on the EPA Toxic Substances Control Act (TSCA) inventory. The following notices are required by 40
CFR 720.36 (C) for those products not on the inventory list:
(EPA)
(i) These products are supplied solely for use in research and development by or under the supervision of a technically
qualified individual as defined in 40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determined. Any information that is or becomes available will be
supplied on an MSDS sheet.
WHMIS ClassificationNot available.
(Canada)
EINECS Number (EEC)Not available.
EEC Risk StatementsR20/21/22- Harmful by inhalation, in contact with skin and if swallowed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Risk Phrases R20/21/22
Safety Phrases S36/37/39
HS Code 2934999090

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

5-(Methacryloyloxy)methyl-1,3-oxathiolane-2-thione
2-Thioxo-1,3-oxathiolan-5-ylmethyl Methacrylate
M1473