(Triphenylphosphoranylidene)acetonitrile

Modify Date: 2024-01-02 20:51:20

(Triphenylphosphoranylidene)acetonitrile structure	Common Name	(Triphenylphosphoranylidene)acetonitrile
	CAS Number	16640-68-9	Molecular Weight	301.322
	Density	1.2±0.1 g/cm3	Boiling Point	465.3±28.0 °C at 760 mmHg
	Molecular Formula	C₂₀H₁₆NP	Melting Point	189-195ºC(lit.)
	MSDS	Chinese USA	Flash Point	235.2±24.0 °C
	Symbol	GHS07	Signal Word	Warning

Name	(Cyanomethylene)Triphenylphosphorane
Synonym	More Synonyms

Density	1.2±0.1 g/cm3
Boiling Point	465.3±28.0 °C at 760 mmHg
Melting Point	189-195ºC(lit.)
Molecular Formula	C₂₀H₁₆NP
Molecular Weight	301.322
Flash Point	235.2±24.0 °C
Exact Mass	301.102051
PSA	33.60000
LogP	3.45
Vapour Pressure	0.0±1.1 mmHg at 25°C
Index of Refraction	1.627
Storage condition	Refrigerator

(Triphenylphosphoranylidene)acetonitrile MSDS(Chinese)

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xi: Irritant;
Risk Phrases	36/37/38
Safety Phrases	26-36
RIDADR	UN 2811 6.1/PG III
WGK Germany	3
Packaging Group	III
HS Code	2931900090

(CYANOMETHYL)TR...

CAS#:15898-47-2

~10%

(Triphenylphosp...

CAS#:16640-68-9

Literature: Burling, Suzanne; Paine, Belinda M.; Nama, Devendrababu; Brown, Victoria S.; Mahon, Mary F.; Prior, Timothy J.; Pregosin, Paul S.; Whittlesey, Michael K.; Williams, Jonathan M. J. Journal of the American Chemical Society, 2007 , vol. 129, # 7 p. 1987 - 1995

(Cyanomethyl)(t...

CAS#:4336-70-3

~80%

(Triphenylphosp...

CAS#:16640-68-9

Literature: Aitken, R. Alan; Al-Awadi, Nouria A.; El-Dusouqui, Osman M.E.; Farrell, Dorcas M.M.; Kumar, Ajith International Journal of Chemical Kinetics, 2006 , vol. 38, # 8 p. 496 - 502

Triphenylphosphine

CAS#:603-35-0

Bromoacetonitrile

CAS#:590-17-0

(Triphenylphosp...

CAS#:16640-68-9

Literature: WO2012/76435 A1, ; Page/Page column 30 ;

Triphenylphosphine

CAS#:603-35-0

(Triphenylphosp...

CAS#:16640-68-9

Literature: International Journal of Chemical Kinetics, , vol. 38, # 8 p. 496 - 502

2-chloroacetonitrile

CAS#:107-14-2

Triphenylphosphine

CAS#:603-35-0

(Triphenylphosp...

CAS#:16640-68-9

Literature: Molecular Crystals and Liquid Crystals (1969-1991), , vol. 150, p. 237 - 246

triphenylcyanom...

CAS#:77785-52-5

(Triphenylphosp...

CAS#:16640-68-9

Literature: Chemistry - A European Journal, , vol. 19, # 7 p. 2311 - 2321

(4-methylphenyl...

CAS#:1124-58-9

methylidene tri...

CAS#:19493-09-5

(Triphenylphosp...

CAS#:16640-68-9

Literature: Justus Liebigs Annalen der Chemie, , p. 1688 - 1693

HS Code	2931900090
Summary	2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

A highly regio- and stereoselective formation of bicyclo[4.2.0]oct-5-ene derivatives through thermal intramolecular [2 + 2] cycloaddition of allenes.

J. Org. Chem. 72 , 4378, (2007)

Thermal [2 + 2] cycloaddition of allenes with an additional multiple bond is described. By simply heating the allenenes or allenynes having a three-atom tether in an appropriate solvent such as dioxan...

2-(Triphenylphosphoranylidene)acetonitrile

EINECS 240-689-7

(Cyanomethylene)triphenylphosphorane

(Triphenylphosphoranylidene)acetonitrile

Acetonitrile, 2-(triphenylphosphoranylidene)-

MFCD00567633