2-(4-Fluorophenoxy)acetohydrazide

Modify Date: 2024-01-10 16:22:30

2-(4-Fluorophenoxy)acetohydrazide Structure
2-(4-Fluorophenoxy)acetohydrazide structure
Common Name 2-(4-Fluorophenoxy)acetohydrazide
CAS Number 1737-62-8 Molecular Weight 184.168
Density 1.3±0.1 g/cm3 Boiling Point 408.8±25.0 °C at 760 mmHg
Molecular Formula C8H9FN2O2 Melting Point 129-134 °C(lit.)
MSDS Chinese USA Flash Point 201.0±23.2 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4-fluorophenoxyacetic acid hydrazide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.3±0.1 g/cm3
Boiling Point 408.8±25.0 °C at 760 mmHg
Melting Point 129-134 °C(lit.)
Molecular Formula C8H9FN2O2
Molecular Weight 184.168
Flash Point 201.0±23.2 °C
Exact Mass 184.064804
PSA 64.35000
LogP 0.10
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.534

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 4-Fluorophenoxyacetic acid hydrazide
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H315:Causes skin irritation
H319:Causes serious eye irritation
H335:May cause respiratory irritation
P261:Avoid breathing dust/fume/gas/mist/vapours/spray
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing

Section3. Composition/information on ingredients.
Ingredient name:4-Fluorophenoxyacetic acid hydrazide
CAS number:1737-62-8

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
Eye contact:
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels, refrigerated.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
No data
Boiling point:
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C8H9FN2O2
Molecular weight: 184.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen fluoride.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2928000090

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Articles2

More Articles
Syntheses and insecticidal activities of novel 2-fluorophenyl-5-aryl/cyclopropyl-1, 3, 4-oxadiazoles Shi W, et al.

J. Fluor. Chem. 106.2 , 173-179, (2000)

Spectroscopic characterization and molecular modeling of novel palladium (II) complexes with carbazates and hydrazides Sousa LM, et al.

J. Mol. Struct. 1097 , 15-22, (2015)

 Synonyms

2-(4-Fluorophenoxy)acetohydrazide
Acetic acid, 2-(4-fluorophenoxy)-, hydrazide
MFCD00082651
4-Fluorophenoxyacetic acid hydrazide
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