[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane

Modify Date: 2024-01-08 18:50:54

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure
[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane structure
 Common Name [2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane
CAS Number 18388-03-9 Molecular Weight 162.732
Density 0.9±0.1 g/cm3 Boiling Point 162.2±20.0 °C at 760 mmHg
Molecular Formula C7H15ClSi Melting Point N/A
MSDS Chinese USA Flash Point 43.3±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07		 Signal Word Warning

 Names

Name 2-(chloromethyl)prop-2-enyl-trimethylsilane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 162.2±20.0 °C at 760 mmHg
Molecular Formula C7H15ClSi
Molecular Weight 162.732
Flash Point 43.3±0.0 °C
Exact Mass 162.063156
LogP 3.75
Vapour Pressure 2.9±0.3 mmHg at 25°C
Index of Refraction 1.425
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases 10-36/37/38
Safety Phrases 26-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3.2

 Synthetic Route

methanesulfonic acid,2-(trimethylsilylmethyl)prop-2-en-1-ol structure

methanesulfonic...

CAS#:74532-54-0

~73%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Clive, Derrick L. J.; Paul, Christine Chua; Wang, Zhongren Journal of Organic Chemistry, 1997 , vol. 62, # 20 p. 7028 - 7032
2-[(Trimethylsilyl)methyl]-2-propen-1-ol structure

2-[(Trimethylsi...

CAS#:81302-80-9

~10%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Jones, Michael D.; Kemmitt, Raymond D. W.; Platt, Andrew W. G. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1986 , p. 1411 - 1418
Trichloro[2-(chloromethyl)-2-propen-1-yl]silane structure

Trichloro[2-(ch...

CAS#:18147-84-7

METHYLMAGNESIUM BROMIDE structure

METHYLMAGNESIUM...

CAS#:75-16-1

~83%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Trost, Barry M.; Buch, Michael; Miller, Maria L. Journal of Organic Chemistry, 1988 , vol. 53, # 20 p. 4887 - 4888
[(Trimethylsilyl)Methyl]Magnesium Chloride structure

[(Trimethylsily...

CAS#:13170-43-9

methyl chloroacetate structure

methyl chloroacetate

CAS#:96-34-4

~49%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Lee, Thomas V.; Porter, John R.; Roden, Frances S. Tetrahedron Letters, 1988 , vol. 29, # 39 p. 5009 - 5012
(Iodomethyl)(trimethyl)silane structure

(Iodomethyl)(tr...

CAS#:4206-67-1

Diethyl malonate structure

Diethyl malonate

CAS#:105-53-3

~%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Tetrahedron Letters, , vol. 21, # 47 p. 4557 - 4560
Trichloro[2-(chloromethyl)-2-propen-1-yl]silane structure

Trichloro[2-(ch...

CAS#:18147-84-7

Methylmagnesium chloride structure

Methylmagnesium...

CAS#:676-58-4

~%

[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane Structure

[2-(Chloromethy...

CAS#:18388-03-9

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , # 3 p. 428 - 435 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 3 p. 461 - 468 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 243,245, 247; engl. Ausg. S. 233, 235, 236

 Synonyms

2-chloromethyl-3-trimethylsilyl-1-propene
2-(chloromethyl)allyl-trimethylsilane
[2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane
2-(Trimethylsilylmethyl)allyl chloride
Silane, [2-(chloromethyl)-2-propen-1-yl]trimethyl-
2-chloromethyl-3-trimethylsilylpropene
MFCD00013253
[2-(Chloromethyl)prop-2-en-1-yl](trimethyl)silane
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Chemsrc provides CAS#:18388-03-9 MSDS, density, melting point, boiling point, structure, etc. Its name is [2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane>> amp version: [2-(Chloromethyl)-2-propen-1-yl](trimethyl)silane

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