(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
(S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) structure
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Common Name | (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) | ||
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| CAS Number | 188264-84-8 | Molecular Weight | 605.759 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C36H54CoN2O2 | Melting Point | >350ºC(lit.) | |
| MSDS | USA | Flash Point | N/A | |
| Name | 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol]-cobalt (1:1) |
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| Synonym | More Synonyms |
| Melting Point | >350ºC(lit.) |
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| Molecular Formula | C36H54CoN2O2 |
| Molecular Weight | 605.759 |
| Exact Mass | 605.351746 |
| PSA | 65.18000 |
| LogP | 9.13700 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
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| Hazard Codes | Xn: Harmful; |
| Risk Phrases | R20/21/22 |
| Safety Phrases | 36/37/39 |
| RIDADR | NONH for all modes of transport |
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~97%
(S,S)-(+)-N,N'-... CAS#:188264-84-8 |
| Literature: Japan Science and Technology Agency; Takasago International Corporation Patent: US2006/173210 A1, 2006 ; Location in patent: Page/Page column 5 ; |
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~95%
(S,S)-(+)-N,N'-... CAS#:188264-84-8 |
| Literature: Chapman; Day; Welker Organometallics, 2000 , vol. 19, # 9 p. 1615 - 1618 |
| Precursor 3 | |
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| DownStream 0 | |
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Asymmetric catalysis with water: efficient kinetic resolution of terminal epoxides by means of catalytic hydrolysis.
Science 277 , 936, (1997) Epoxides are versatile building blocks for organic synthesis. However, terminal epoxides are arguably the most important subclass of these compounds, and no general and practical method exists for the... |
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Jacobsen, E.N. et al.
Tetrahedron Lett. 38 , 773, (1997)
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| (-)-1,2-bis((2S,5S)-2,5-diisiopropyl phosphorano) benzene |
| (S,S)-Fmoc-trans-2-aminocyclopentanecarboxylic acid-OH |
| (S,S)-Jocobsen's catalyst |
| (1S,2S)-2-(9H-fluoren-9-ylmethoxycarbonyl)amino-cyclopentanecarboxylic acid |
| Fmoc-(S,S)-2-aminocyclopentanecarboxylic acid |
| (1S,2S)-2-{[(9H-fluoren-9-ylmethoxy)carbonyl]amino}cyclopentane-1-carboxylic acid |
| 1,2-bis(2,5-diisopropylphospholano)benzene |
| MFCD01631278 |
| (S,S)-Co-salen complex |
| Fmoc-(S,S)-ACPC |
| (S,S)-iPrDuPhos |
| Cyclopentanecarboxylicacid,2-[[(9H-fluoren-9-ylmethoxy)carbonyl]amino]-,(1S,2S) |
| (S,S)-(-)-N-N'-bis(3,5-di-tert-butylsalicylidine)-1,2-cyclohexanediaminocobalt-II |
| (R,R)-i-Pr-DuPhos |
| (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) |
| Jacobsen's (S,S)-(salen)Co(III) catalyst |
| (S,S)-(salen)Co(II) |
| 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] - cobalt (1:1) |
| (S,S)-Co-Salen |
| (S,S)-Fmoc-trans-2-aminocyclopentanecarboxylic acid |
| (S,S)-Fmoc-ACPC-OH |
| Phenol, 2,2'-[(1S,2S)-1,2-cyclohexanediylbis[nitrilo(E)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)-, cobalt salt (1:1) |
| (S,S)-(+)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) |