1-Methyl-1H-indole-3-carbaldehyde

Modify Date: 2024-01-02 15:58:05

1-Methyl-1H-indole-3-carbaldehyde Structure
1-Methyl-1H-indole-3-carbaldehyde structure
Common Name 1-Methyl-1H-indole-3-carbaldehyde
CAS Number 19012-03-4 Molecular Weight 159.185
Density 1.1±0.1 g/cm3 Boiling Point 318.7±15.0 °C at 760 mmHg
Molecular Formula C10H9NO Melting Point 70-72 °C(lit.)
MSDS USA Flash Point 146.5±20.4 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 1-methylindole-3-carbaldehyde
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 318.7±15.0 °C at 760 mmHg
Melting Point 70-72 °C(lit.)
Molecular Formula C10H9NO
Molecular Weight 159.185
Flash Point 146.5±20.4 °C
Exact Mass 159.068420
PSA 22.00000
LogP 1.96
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.585

 MSDS

Name: 1-Methylindole-3-carboxaldehyde 97% Material Safety Data Sheet
Synonym:
CAS: 19012-03-4
Section 1 - Chemical Product MSDS Name:1-Methylindole-3-carboxaldehyde 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
19012-03-4 1-Methylindole-3-carboxaldehyde 97% 242-750-3
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 19012-03-4: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Light yellow to orange cryst. powder and chunks
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 70 - 72 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in acetone, diethyl ester
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 19012-03-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methylindole-3-carboxaldehyde - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 19012-03-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 19012-03-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 19012-03-4 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2933990090

 Synthetic Route

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles3

More Articles
N-Acetyl-2-hydroxy-N'-[methoxy(1-methylindol-2-yl)methyl]benzohydrazide.

Acta Crystallogr. Sect. E Struct. Rep. Online 64(Pt 9) , o1824, (2008)

In the crystal structure of the title Schiff-base, C(20)H(21)N(3)O(4), the amino group forms an N-H⋯O hydrogen bond to the acetyl group of an adjacent mol-ecule, forming a zigzag chain. The 2-hydr-oxy...

(Z)-3-(1-Methyl-1H-indol-3-yl)-2-(thiophen-3-yl)acrylonitrile.

Acta Crystallogr. C 60(Pt 3) , o217-8, (2004)

The title compound, C16H12N2S, has been synthesized by base-catalyzed condensation of 1-methylindole-3-carboxaldehyde with thiophene-3-acetonitrile. The product assumes an approximately planar Z confi...

Preliminary analysis of the 1H-and 13C-NMR spectra of poly (3-vinyl-1-methylindole). Trumbo DL.

Polymer Bull. 37(1) , 75-80, (1996)

 Synonyms

MFCD00014570
3-Formyl-1-methylindole
1H-Indole-3-carboxaldehyde,1-methyl
1-Methyl-1H-indole-3-carbaldehyde
EINECS 242-750-3
Indole-3-carboxaldehyde, 1-methyl-
3-formyl N-methyl indole
N-Methyl-3-indolecarboxaldehyde
N-methylindole-3-carboxaldehyde
1H-Indole-3-carboxaldehyde, 1-methyl-
N-Methyl-3-formylindole
1-methyl-1H-indol-3-carboxaldehyde
1-Methyl-3-formylindole
1-methyl-indole-3-carbaldehyde
1-Methylindole-3-carboxaldehyde
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