7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)-

Modify Date: 2024-01-10 14:54:46

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure
7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- structure
Common Name 7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)-
CAS Number 1984-43-6 Molecular Weight 212.19900
Density 1.287g/cm3 Boiling Point 288.9ºC at 760 mmHg
Molecular Formula C10H12O5 Melting Point N/A
MSDS N/A Flash Point 124.9ºC

 Names

Name dimethyl (1R,2S,3R,4S)-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.287g/cm3
Boiling Point 288.9ºC at 760 mmHg
Molecular Formula C10H12O5
Molecular Weight 212.19900
Flash Point 124.9ºC
Exact Mass 212.06800
PSA 61.83000
Vapour Pressure 0.00227mmHg at 25°C
Index of Refraction 1.504

 Synthetic Route

~54%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Umezawa, Naoki; Tanaka, Kumi; Urano, Yasuteru; Kikuchi, Kazuya; Higuchi, Tsunehiko; Nagano, Tetsuo Angewandte Chemie - International Edition, 1999 , vol. 38, # 19 p. 2899 - 2901

~%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: McCluskey, Adam; Keane, Mirella A.; Walkom, Cecilia C.; Bowyer, Michael C.; Sim, Alistair T.R.; Young, David J.; Sakoff, Jennette A. Bioorganic and Medicinal Chemistry Letters, 2002 , vol. 12, # 3 p. 391 - 393

~68%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Hanson, Peter; Wren, Stephen A. C. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1990 , # 7 p. 2089 - 2097

~%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Bloch, R.; Guibe-Jampel, E.; Girard, C. Tetrahedron Letters, 1985 , vol. 26, # 34 p. 4087 - 4090

~45%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Brown, Richard T.; Jameson, Simon B.; Ouali, Dehimi; Tattersall, Peter I. Journal of Chemical Research - Part S, 2000 , # 4 p. 176 - 178

~%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Riobe; Jolivet Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1956 , vol. 243, p. 164 Full Text Show Details Jolivet Annales de Chimie (Cachan, France), 1960 , vol. <13> 5, p. 1165,1187 Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1956 , vol. 243, p. 2085

~%

7-Oxabicyclo(2.2.1)hept-5-ene-2,3-dicarboxylic acid, dimethyl ester, (exo,exo)- Structure

7-Oxabicyclo(2....

CAS#:1984-43-6

Literature: Schmitz, C.; Aubry, J. M.; Rigaudy, J. Tetrahedron, 1982 , vol. 38, # 10 p. 1425 - 1430

 Synonyms

dimethyl 7-oxanorbornene-2,3-dicarboxylate
Proline,5-oxo-3-phenyl-,trans
trans-2-Carboxy-3-phenyl-pyrrolidon-5