3-(2-thienyl)pyrazole structure
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Common Name | 3-(2-thienyl)pyrazole | ||
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CAS Number | 19933-24-5 | Molecular Weight | 150.20100 | |
Density | 1.297g/cm3 | Boiling Point | 152 °C (1.6 mmHg) | |
Molecular Formula | C7H6N2S | Melting Point | 97-99 °C | |
MSDS | USA | Flash Point | 143.4ºC |
Name | 5-thiophen-2-yl-1H-pyrazole |
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Synonym | More Synonyms |
Density | 1.297g/cm3 |
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Boiling Point | 152 °C (1.6 mmHg) |
Melting Point | 97-99 °C |
Molecular Formula | C7H6N2S |
Molecular Weight | 150.20100 |
Flash Point | 143.4ºC |
Exact Mass | 150.02500 |
PSA | 56.92000 |
LogP | 2.13820 |
Vapour Pressure | 0.00139mmHg at 25°C |
Index of Refraction | 1.641 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: No information regarding eye irritation and other potential effects was found. Skin: No information regarding skin irritation and other potential effects was found. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: The toxicological properties of this substance have not been fully investigated. Chronic: No information found. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water fog, dry chemical, carbon dioxide, or regular foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a cool, dry place. Keep containers tightly closed. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 19933-24-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Powder Color: light green Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 152 deg C @ 1.60mmHg Freezing/Melting Point: 97.00 - 98.00 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H6N2S Molecular Weight: 150.20 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Strong oxidizing agents, strong bases. Hazardous Decomposition Products: Not available. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 19933-24-5 unlisted. LD50/LC50: Not available. Carcinogenicity: 3-(2-Thienyl) Pyrazole - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 24/25 Avoid contact with skin and eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 19933-24-5: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 19933-24-5 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 19933-24-5 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi:Irritant; |
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Risk Phrases | R36/37/38 |
Safety Phrases | S37/39-S24/25 |
HS Code | 2934999090 |
~69% 3-(2-thienyl)py... CAS#:19933-24-5 |
Literature: Al-Omran, Fatima; Al-Awadi, Nouria; El-Khair, Adel Abou; Elnagdi, Mohammed Hilmy Organic Preparations and Procedures International, 1997 , vol. 29, # 3 p. 285 - 292 |
~% 3-(2-thienyl)py... CAS#:19933-24-5 |
Literature: Tetrahedron Letters, , vol. 39, # 20 p. 3287 - 3290 |
~% 3-(2-thienyl)py... CAS#:19933-24-5 |
Literature: Organic Preparations and Procedures International, , vol. 29, # 3 p. 285 - 292 |
~% 3-(2-thienyl)py... CAS#:19933-24-5 |
Literature: Journal of Chemical Research, Miniprint, , # 1 p. 151 - 163 |
HS Code | 2934999090 |
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Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
MFCD00178757 |
3-thiophen-2-yl-1h-pyrazole |
3-(2-THIENYL)PYRAZOLE |
2-pyrazol-3-ylthiophene |