2-Bromo-4'-cyanoacetophenone structure
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Common Name | 2-Bromo-4'-cyanoacetophenone | ||
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CAS Number | 20099-89-2 | Molecular Weight | 224.054 | |
Density | 1.6±0.1 g/cm3 | Boiling Point | 342.4±22.0 °C at 760 mmHg | |
Molecular Formula | C9H6BrNO | Melting Point | 92-96 °C(lit.) | |
MSDS | USA | Flash Point | 160.9±22.3 °C | |
Symbol |
GHS05, GHS07 |
Signal Word | Danger |
Name | 4-(2-bromoacetyl)benzonitrile |
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Synonym | More Synonyms |
Density | 1.6±0.1 g/cm3 |
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Boiling Point | 342.4±22.0 °C at 760 mmHg |
Melting Point | 92-96 °C(lit.) |
Molecular Formula | C9H6BrNO |
Molecular Weight | 224.054 |
Flash Point | 160.9±22.3 °C |
Exact Mass | 222.963272 |
PSA | 40.86000 |
LogP | 1.75 |
Vapour Pressure | 0.0±0.8 mmHg at 25°C |
Index of Refraction | 1.590 |
Symbol |
GHS05, GHS07 |
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Signal Word | Danger |
Hazard Statements | H302-H312-H314-H332 |
Precautionary Statements | P280-P305 + P351 + P338-P310 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | C:Corrosive; |
Risk Phrases | R20/21/22;R34 |
Safety Phrases | S26-S27-S36/37/39-S45 |
RIDADR | UN 2928 6.1/PG 2 |
WGK Germany | 3 |
Packaging Group | II |
Hazard Class | 6.1 |
HS Code | 2926909090 |
~99% 2-Bromo-4'-cyan... CAS#:20099-89-2 |
Literature: Kallmayer, Hans-Joerg; Wagner, Eugen Archiv der Pharmazie (Weinheim, Germany), 1980 , vol. 313, # 4 p. 315 - 323 |
~45% 2-Bromo-4'-cyan... CAS#:20099-89-2 |
Literature: Journal of Medicinal Chemistry, , vol. 54, # 12 p. 4042 - 4056 |
~65% 2-Bromo-4'-cyan... CAS#:20099-89-2 |
Literature: Chen, Zheng-Wang; Ye, Dong-Nai; Ye, Min; Zhou, Zhong-Gao; Li, Shen-Huan; Liu, Liang-Xian Tetrahedron Letters, 2014 , vol. 55, # 7 p. 1373 - 1375 |
~59% 2-Bromo-4'-cyan... CAS#:20099-89-2 |
Literature: Tada, Norihiro; Ban, Kazunori; Hirashima, Shin-Ichi; Miura, Tsuyoshi; Itoh, Akichika Organic and Biomolecular Chemistry, 2010 , vol. 8, # 20 p. 4701 - 4704 |
~33% 2-Bromo-4'-cyan... CAS#:20099-89-2 |
Literature: Tetrahedron Letters, , vol. 53, # 2 p. 191 - 195 |
Precursor 3 | |
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DownStream 10 | |
HS Code | 2926909090 |
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Summary | HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
Direct synthesis of α-bromoketones from alkylarenes by aerobic visible light photooxidation.
Org. Biomol. Chem. 8(20) , 4701-4, (2010) The direct synthesis of α-bromoketones from alkylarenes by aerobic photooxidation with hydrobromic acid is reported. The key success for this direct oxidative reaction is due to control of bromination... |
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Application of DMF–methyl sulfate adduct in the regioselective synthesis of 3-acylated indolizines. Przewloka T, et al.
Tetrahedron Lett. 48(33) , 5739-5742, (2007)
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Synthesis and antifungal activity of novel thiazole-containing triazole antifungals. II. Optically active ER-30346 and its derivatives. Tsuruoka, Akihiko, et al.
Chem. Pharm. Bull. 46(4) , 623-630, (1998)
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2-bromo-4'-cyano-acetophenone |
Benzonitrile, 4-(bromoacetyl)- |
MFCD00052931 |
4-(Bromacetyl)benzolcarbonitril |
2-bromo-4'-CN-acetophenone |
4-(Bromoacetyl)benzonitrile |
2-Bromo-4'-cyanoacetophenone |
p-Cyanophenacyl bromide |
2-Br-4'-CN-acetophenone |
4-(2-Bromoacetyl)benzonitrile |
4-Cyanophenacyl bromide |
Benzonitrile, 4-(2-bromoacetyl)- |
4-(2-bromo-acetyl)-benzonitrile |