cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione structure
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Common Name | cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione | ||
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CAS Number | 21170-10-5 | Molecular Weight | 166.21700 | |
Density | 1.142g/cm3 | Boiling Point | 257.5ºC at 760 mmHg | |
Molecular Formula | C10H14O2 | Melting Point | 228-230ºC(lit.) | |
MSDS | USA | Flash Point | 95ºC |
Use of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dioneOlefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds. |
Name | 3a,6a-dimethyl-1,3,4,6-tetrahydropentalene-2,5-dione |
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Synonym | More Synonyms |
Density | 1.142g/cm3 |
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Boiling Point | 257.5ºC at 760 mmHg |
Melting Point | 228-230ºC(lit.) |
Molecular Formula | C10H14O2 |
Molecular Weight | 166.21700 |
Flash Point | 95ºC |
Exact Mass | 166.09900 |
PSA | 34.14000 |
LogP | 1.72480 |
Vapour Pressure | 0.0145mmHg at 25°C |
Index of Refraction | 1.522 |
~83% cis-1,5-dimethy... CAS#:21170-10-5 |
Literature: Coates, Robert M.; Shach, Shrenik K.; Mason, Robert W. Journal of the American Chemical Society, 1982 , vol. 104, # 8 p. 2198 - 2208 |
Microwave-assisted regioselective olefinations of cyclic mono-and di-ketones with a stabilized phosphorus ylide. Wu J, et al.
Tetrahedron 62(19) , 4643-50, (2006)
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DITHIOCARBOXYLIERUNGSREAKTIONEN VON cis-BICYCLO [3.3. 0] OCTAN-3, 7-DIONEN. MOLEKÜL-UND KRISTALLSTRUKTUR VON cis-2, 6-BIS (DIMETHYLTHIO-METHYLEN)-BICYCLO [3.3. 0] OCTAN-3, 7-DION. Dölling W, et al.
Phosphorus. Sulfur. Silicon Relat. Elem. 113(1-4) , 263-74, (1996)
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1,5-dimethyl-bicyclo<3.3.0>octandion |
1,5-Dimethylbicyclo<3.3.0>octan-3,7-dione |
cis-3a,6a-Dimethyltetrahydropentalene-2,5(1H,3H)-dione |
EINECS 244-255-8 |
1,5-Dimethylbicyclo<3.3.0>octan-3,7-dion |
rel-(3aR,6aR)-3a,6a-diMethyl-octahydropentalene-2,5-dione |
3A,6A-DIMETHYLPERHYDROPENTALENE-2,5-DIONE |
1,5-dimethylbicyclo<3.3.0>octane-3,7-dione |
cis-tetrahydro-3a,6a-dimethylpentalene-2,5(1H,3H)-dione |
cis-1,5-dimethylbicyclo<3.3.0>octane-3,7-dione |
MFCD00003772 |