TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE

Modify Date: 2024-01-05 07:42:46

TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Structure
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE structure
Common Name TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
CAS Number 21797-13-7 Molecular Weight 444.23700
Density N/A Boiling Point N/A
Molecular Formula C8H12B2F8N4Pd Melting Point 230ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name acetonitrile,palladium(2+),ditetrafluoroborate
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 230ºC
Molecular Formula C8H12B2F8N4Pd
Molecular Weight 444.23700
Exact Mass 444.01600
PSA 95.16000
LogP 4.71952
Appearance of Characters Powder | Yellow
Storage condition 2-8°C
Water Solubility Soluble in water

 MSDS

Name: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet
Synonym:
CAS: 21797-13-7
Section 1 - Chemical Product MSDS Name:Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
21797-13-7 Tetrakis(acetonitrile)palladium(II) te unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.Air sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 21797-13-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 230 deg C (dec.)
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C8H12B2F8N4Pd
Molecular Weight: 444.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas, boron oxides.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 21797-13-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetrakis(acetonitrile)palladium(II) tetrafluoroborate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 21797-13-7: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21797-13-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21797-13-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H332
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R20
Safety Phrases S22-S38-S36/37/39
RIDADR UN2811
WGK Germany 3
Packaging Group III
HS Code 29310099

 Articles7

More Articles
Extended-chain, multinuclear transition metal complexes bridged by cyanodiazenido(1-), [N=N-C[triple bond, length as m-dash]N]-, ligands.

Dalton Trans. (32) , 3538-45, (2007)

Extended-chain complexes containing multiple transition metal centres linked by conjugated micro-cyanodiazenido(1-) ligands [N=N-C[triple bond, length as m-dash]N]- have been obtained by reaction of t...

Unique 2:1 complex with a trans-chelating bis-pyridine ligand.

Inorg. Chem. 41(8) , 2296-300, (2002)

Gorman, C. B.; Vest, R. W. et al.

Macromolecules 32 , 4157, (1999)

 Synonyms

[Pd(NCMe)4][BF4]2
[(MeCN)4Pd][BF4]2
ditetrafluoroborate
[Pd(MeCN)4](tetrafluoroborate)2
MFCD00043297
[Pd(CH3CN)4][BF4]2
[Pd(acetonitrile)4](BF4)2
[Pd(MeCN)4](BF4)2
Palladium(II) tetrafluoroborate tetraacetonitrile complex
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