N-PHENYL-2,3-NAPHTHALIMIDE

Modify Date: 2024-01-02 00:52:12

N-PHENYL-2,3-NAPHTHALIMIDE Structure
N-PHENYL-2,3-NAPHTHALIMIDE structure
Common Name N-PHENYL-2,3-NAPHTHALIMIDE
CAS Number 21815-18-9 Molecular Weight 273.28500
Density 1.36g/cm3 Boiling Point 482.8ºC at 760mmHg
Molecular Formula C18H11NO2 Melting Point 278-284ºC
MSDS N/A Flash Point 231.5ºC

 Names

Name 2-phenylbenzo[f]isoindole-1,3-dione
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.36g/cm3
Boiling Point 482.8ºC at 760mmHg
Melting Point 278-284ºC
Molecular Formula C18H11NO2
Molecular Weight 273.28500
Flash Point 231.5ºC
Exact Mass 273.07900
PSA 37.38000
LogP 3.70540
Vapour Pressure 1.78E-09mmHg at 25°C
Index of Refraction 1.726

 MSDS

Name: N-Phenyl-2 3-naphthalimide 98% Material Safety Data Sheet
Synonym: N-Phenylnaphthalene-2,3-dicarboximide; 2-Phenyl-1H-benz[f]isoindole-1,3(2H)-dion
CAS: 21815-18-9
Section 1 - Chemical Product MSDS Name:N-Phenyl-2 3-naphthalimide 98% Material Safety Data Sheet
Synonym:N-Phenylnaphthalene-2,3-dicarboximide; 2-Phenyl-1H-benz[f]isoindole-1,3(2H)-dion

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
21815-18-9 N-Phenyl-2,3-naphthalimide 98% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 21815-18-9: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Not available.
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C18H11NO2
Molecular Weight: 273.29

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 21815-18-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-Phenyl-2,3-naphthalimide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 21815-18-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21815-18-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21815-18-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases S24/25
HS Code 2925190090

 Synthetic Route

~73%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Perry, Robert J.; Turner, S. Richard Journal of Organic Chemistry, 1991 , vol. 56, # 23 p. 6573 - 6579

~28%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Ishihara Sangyo Kaisha Ltd. Patent: US6429212 B1, 2002 ; US 6429212 B1

~%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Cava et al. Journal of the American Chemical Society, 1959 , vol. 81, p. 6458

~34%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Shi, Xian-Ying; Renzetti, Andrea; Kundu, Soumen; Li, Chao-Jun Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 723 - 728

~%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Perry, Robert J.; Turner, S. Richard Journal of Organic Chemistry, 1991 , vol. 56, # 23 p. 6573 - 6579

~%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Murahashi et al. Nippon Kagaku Zasshi, 1958 , vol. 79, p. 68,79 Chem.Abstr., 1960 , p. 5558

~%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Freund; Fleischer Justus Liebigs Annalen der Chemie, 1913 , vol. 402, p. 70 Justus Liebigs Annalen der Chemie, 1910 , vol. 373, p. 323

~%

N-PHENYL-2,3-NAPHTHALIMIDE Structure

N-PHENYL-2,3-NA...

CAS#:21815-18-9

Literature: Cava et al. Journal of the American Chemical Society, 1959 , vol. 81, p. 6458

 Customs

HS Code 2925190090
Summary 2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

N-phenyl-2,3-naphthalimide
N-Phenyl-naphthalin-2,3-dicarbonsaeure-imid
N-phenylnaphthalene-2,3-dicarboximide
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