Oxirane,2-[(4-methylphenoxy)methyl]-

Modify Date: 2024-01-07 10:38:15

Oxirane,2-[(4-methylphenoxy)methyl]- Structure
Oxirane,2-[(4-methylphenoxy)methyl]- structure
 Common Name Oxirane,2-[(4-methylphenoxy)methyl]-
CAS Number 2186-24-5 Molecular Weight 164.20100
Density 1.094g/cm3 Boiling Point 258ºC at 760mmHg
Molecular Formula C10H12O2 Melting Point N/A
MSDS N/A Flash Point 104.3ºC

 Names

Name 2-[(4-methylphenoxy)methyl]oxirane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.094g/cm3
Boiling Point 258ºC at 760mmHg
Molecular Formula C10H12O2
Molecular Weight 164.20100
Flash Point 104.3ºC
Exact Mass 164.08400
PSA 21.76000
LogP 1.77260
Vapour Pressure 0.0227mmHg at 25°C
Index of Refraction 1.533

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ3701000
CHEMICAL NAME :
Propane, 1,2-epoxy-3-(p-tolyloxy)-
CAS REGISTRY NUMBER :
2186-24-5
BEILSTEIN REFERENCE NO. :
0117187
LAST UPDATED :
199710
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C10-H12-O2
MOLECULAR WEIGHT :
164.22
WISWESSER LINE NOTATION :
T3OTJ B1OR D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
100 ug/plate
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 172,105,1986 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 10 ppm (70 mg/m3) JAN 1993 OEL-SWEDEN:TWA 10 ppm (70 mg/m3);STEL 15 ppm (100 mg/m3) JAN 1993

 Safety Information

Hazard Codes Xn
HS Code 2910900090

 Synthetic Route

p-Cresol structure

p-Cresol

CAS#:106-44-5

Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~80%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Khadilkar, Bhushan M.; Bendale, Pravin M. Synthetic Communications, 1997 , vol. 27, # 12 p. 2051 - 2056
2-[(2-bromo-4-methyl-phenoxy)methyl]oxirane structure

2-[(2-bromo-4-m...

CAS#:68224-00-0

~80%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Bhuvaneswari; Venkatachalam; Balasubramanian Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1499 - 1502
p-Cresol structure

p-Cresol

CAS#:106-44-5

Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~84%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

1-Chloro-3-(4-methylphenoxy)propan-2-ol structure

1-Chloro-3-(4-m...

CAS#:4769-74-8

Literature: Pchelka, Beata K.; Loupy, Andre; Petit, Alain Tetrahedron, 2006 , vol. 62, # 47 p. 10968 - 10979
2-Bromo-4-methylphenol structure

2-Bromo-4-methy...

CAS#:6627-55-0

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Bhuvaneswari; Venkatachalam; Balasubramanian Tetrahedron Letters, 1992 , vol. 33, # 11 p. 1499 - 1502
p-Cresol structure

p-Cresol

CAS#:106-44-5

1,3-Dichloro-2-propanol structure

1,3-Dichloro-2-...

CAS#:96-23-1

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Poulenc Freres; Fourneau Patent: DE228205 ; Fortschr. Teerfarbenfabr. Verw. Industriezweige, vol. 10, p. 1174
Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: v. Lindeman Chemische Berichte, 1891 , vol. 24, p. 2148 Full Text Show Details Boyd; Marle Journal of the Chemical Society, 1908 , vol. 93, p. 840 Journal of the Chemical Society, 1909 , vol. 95, p. 1807
p-Cresol structure

p-Cresol

CAS#:106-44-5

1-Chloro-3-(4-methylphenoxy)propan-2-ol structure

1-Chloro-3-(4-m...

CAS#:4769-74-8

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Chlebicki, Jan; Shiman, Larisa Yu.; Guskov, Andrey K.; Makarov, Mikhail G.; Shvets, Valerij F. International Journal of Chemical Kinetics, 1997 , vol. 29, # 1 p. 73 - 79
p-Cresol structure

p-Cresol

CAS#:106-44-5

Epichlorohydrin structure

Epichlorohydrin

CAS#:106-89-8

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

1,3-Dichloro-2-propanol structure

1,3-Dichloro-2-...

CAS#:96-23-1

Detail
Literature: Chlebicki, Jan; Shiman, Larisa Yu.; Guskov, Andrey K.; Makarov, Mikhail G.; Shvets, Valerij F. International Journal of Chemical Kinetics, 1997 , vol. 29, # 1 p. 73 - 79
Peracetic acid structure

Peracetic acid

CAS#:79-21-0

Benzene,1-methyl-4-(2-propen-1-yloxy)- structure

Benzene,1-methy...

CAS#:23431-48-3

~%

Oxirane,2-[(4-methylphenoxy)methyl]- Structure

Oxirane,2-[(4-m...

CAS#:2186-24-5

Literature: Panssewitsch-Koljada; Ideltschik Zhurnal Obshchei Khimii, 1955 , vol. 25, p. 2215,2219, 2220 J. Gen. Chem. USSR (Engl. Transl.), 1955 , vol. 25, p. 2177,2181

 Customs

HS Code 2910900090
Summary 2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

 Synonyms

1-p-tolyloxy-2,3-epoxypropane
p-Tolylglycidyl ether
1-(4-methylphenoxy)-2,3-epoxypropane
PARA-CRESYLGLYCIDYLETHER
2-(4-Methyl-phenoxymethyl)-oxirane
(RS)-1,2-epoxy-3-(4-methylphenoxy)propane
p-cresylglycidylether
2-P-TOLYLOXYMETHYL-OXIRANE
Kresylglycidyleter
3-(4-methylphenoxy)-1,2-epoxypropane
4-methylphenyl 2,3-epoxypropyl ether
Glycidyl p-tolyl ether
1,2-epoxy-3-(4-methylphenoxy)propane
p-cresolglycidylether
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