2-Naphthalenol,1-[(S)-aminophenylmethyl]-

Modify Date: 2024-01-08 12:05:52

2-Naphthalenol,1-[(S)-aminophenylmethyl]- Structure
2-Naphthalenol,1-[(S)-aminophenylmethyl]- structure
Common Name 2-Naphthalenol,1-[(S)-aminophenylmethyl]-
CAS Number 219897-38-8 Molecular Weight 249.30700
Density N/A Boiling Point 451.1ºC at 760mmHg
Molecular Formula C17H15NO Melting Point 133-137ºC
MSDS N/A Flash Point 226.6ºC

 Names

Name 1-[(S)-amino(phenyl)methyl]naphthalen-2-ol
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 451.1ºC at 760mmHg
Melting Point 133-137ºC
Molecular Formula C17H15NO
Molecular Weight 249.30700
Flash Point 226.6ºC
Exact Mass 249.11500
PSA 46.25000
LogP 4.29380
Vapour Pressure 9.38E-09mmHg at 25°C

 MSDS

Name: (S)-(+)-1-(alpha-Aminobenzyl)-2-naphthol 98% Material Safety Data Sheet
Synonym: (S)-Betti bas
CAS: 219897-38-8
Section 1 - Chemical Product MSDS Name:(S)-(+)-1-(alpha-Aminobenzyl)-2-naphthol 98% Material Safety Data Sheet
Synonym:(S)-Betti bas

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
219897-38-8 (S)-(+)-1-(alpha-Aminobenzyl)-2-naphth 98% unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep refrigerated. (Store below 4C/39F.) Store in a tightly closed container. Store in a dry area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 219897-38-8: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white to off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 133 - 137 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 259 deg C
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C17H15NO
Molecular Weight: 249.31

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 219897-38-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(S)-(+)-1-(alpha-Aminobenzyl)-2-naphthol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 36 Wear suitable protective clothing.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 219897-38-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 219897-38-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 219897-38-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 37/39-36
HS Code 2922299090

 Synthetic Route

~42%

2-Naphthalenol,1-[(S)-aminophenylmethyl]- Structure

2-Naphthalenol,...

CAS#:219897-38-8

Literature: Periasamy, Mariappan; Anwar, Shaik; Reddy, Meda Narsi Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2009 , vol. 48, # 9 p. 1261 - 1273

~%

2-Naphthalenol,1-[(S)-aminophenylmethyl]- Structure

2-Naphthalenol,...

CAS#:219897-38-8

Literature: Synthesis (Germany), , vol. 45, # 7 art. no. SS-2012-H0910-OP, p. 899 - 902

~%

2-Naphthalenol,1-[(S)-aminophenylmethyl]- Structure

2-Naphthalenol,...

CAS#:219897-38-8

Literature: Synthesis (Germany), , vol. 45, # 7 art. no. SS-2012-H0910-OP, p. 899 - 902

 Customs

HS Code 2922299090
Summary 2922299090. other amino-naphthols and other amino-phenols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Synonyms

unii-690biu4wik
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