1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethan-1-one structure
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Common Name | 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethan-1-one | ||
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CAS Number | 22776-09-6 | Molecular Weight | 192.21100 | |
Density | 1.146g/cm3 | Boiling Point | 120°C/0.5mm | |
Molecular Formula | C11H12O3 | Melting Point | N/A | |
MSDS | N/A | Flash Point | 120°C/0.5mm |
Use of 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethan-1-one |
Name | 1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)ethanone |
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Synonym | More Synonyms |
Density | 1.146g/cm3 |
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Boiling Point | 120°C/0.5mm |
Molecular Formula | C11H12O3 |
Molecular Weight | 192.21100 |
Flash Point | 120°C/0.5mm |
Exact Mass | 192.07900 |
PSA | 35.53000 |
LogP | 2.05050 |
Vapour Pressure | 0.00019mmHg at 25°C |
Index of Refraction | 1.528 |
Synonym:3,4-(Trimethylenedioxy)aceto phenon Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: None Listed. Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Not available. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 22776-09-6: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: orange Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C11H12O3 Molecular Weight: 192 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 22776-09-6 unlisted. LD50/LC50: Not available. Carcinogenicity: 1-(3,4-Dihydro-2H-1,5-benzodioxepin-7-yl)ethan-1-one - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: Not available. Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# 22776-09-6: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 22776-09-6 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 22776-09-6 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi: Irritant; |
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Risk Phrases | 22 |
Safety Phrases | S24/25 |
HS Code | 2932999099 |
~90% 1-(3,4-dihydro-... CAS#:22776-09-6 |
Literature: Huang, Wei-Bin; Guo, Ying; Jiang, Jian-An; Pan, Xian-Dao; Liao, Dao-Hua; Ji, Ya-Fei Synlett, 2013 , vol. 24, # 6 art. no. ST-2013-W0052-L, p. 741 - 746 |
~94% 1-(3,4-dihydro-... CAS#:22776-09-6 |
Literature: Huang, Wei-Bin; Guo, Ying; Jiang, Jian-An; Pan, Xian-Dao; Liao, Dao-Hua; Ji, Ya-Fei Synlett, 2013 , vol. 24, # 6 art. no. ST-2013-W0052-L, p. 741 - 746 |
~% 1-(3,4-dihydro-... CAS#:22776-09-6 |
Literature: Synlett, , vol. 24, # 6 art. no. ST-2013-W0052-L, p. 741 - 746 |
Precursor 5 | |
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DownStream 4 | |
HS Code | 2932999099 |
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Summary | 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
3,4-Trimethylendioxy-acetophenon |
MFCD00114700 |
7-Acetyl-3,4-dihydro-1,5-benzodioxepin |
3,4-Dihydro-1,5-benzodioxepin-7-yl-methyl-keton |