Methyl nitroacetate structure
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Common Name | Methyl nitroacetate | ||
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CAS Number | 2483-57-0 | Molecular Weight | 119.076 | |
Density | 1.3±0.1 g/cm3 | Boiling Point | 196.5±0.0 °C at 760 mmHg | |
Molecular Formula | C3H5NO4 | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | 105.0±0.0 °C | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | methyl 2-nitroacetate |
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Synonym | More Synonyms |
Density | 1.3±0.1 g/cm3 |
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Boiling Point | 196.5±0.0 °C at 760 mmHg |
Molecular Formula | C3H5NO4 |
Molecular Weight | 119.076 |
Flash Point | 105.0±0.0 °C |
Exact Mass | 119.021858 |
PSA | 72.12000 |
LogP | 0.34 |
Vapour Pressure | 0.4±0.3 mmHg at 25°C |
Index of Refraction | 1.418 |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
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Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | Xi:Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S36-S37/39 |
RIDADR | NONH for all modes of transport |
WGK Germany | 2 |
RTECS | AJ1093000 |
HS Code | 2915900090 |
HS Code | 2915900090 |
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Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |
Experimental and theoretical studies of Diels-Alder reaction between methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate and cyclopentadiene. Jasinski R, et al.
Monatsh. Chem 144(3) , 327-35, (2013)
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Catalytic intermolecular allylic C-H alkylation.
J. Am. Chem. Soc. 130 , 14090-14091, (2008) The first electrophilic Pd(II)-catalyzed allylic C H alkylation is reported, providing a novel method for formation of sp3-sp3 C C bonds directly from C H bonds. A wide range of aromatic and heteroaro... |
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Expedient synthesis of cyclopropane alpha-amino acids by the catalytic asymmetric cyclopropanation of alkenes using iodonium ylides derived from methyl nitroacetate.
J. Am. Chem. Soc. 127(51) , 18014-5, (2005) A highly enantioselective (up to 97.5% ee) and diastereoselective (95:5 dr trans/cis) Cu(I)-catalyzed cyclopropanation of alkenes using phenyliodonium ylide generated in situ from iodosobenzene and me... |
Acetic acid, 2-nitro-, methyl ester |
methyl 2-nitroethanoate |
MFCD00075480 |
Methyl 2-nitroacetate |
Methyl nitroacetate |
Methyl α nitroacetate |
EINECS 219-622-0 |
NO2CH2CO2Me |
ACETIC ACID,NITRO-,METHYL ESTER |
Nitroacetic acid methyl ester |