4-(Benzyloxy)pyridine 1-oxide

Modify Date: 2024-01-02 17:17:09

4-(Benzyloxy)pyridine 1-oxide Structure
4-(Benzyloxy)pyridine 1-oxide structure
Common Name 4-(Benzyloxy)pyridine 1-oxide
CAS Number 2683-66-1 Molecular Weight 201.221
Density 1.1±0.1 g/cm3 Boiling Point 415.3±20.0 °C at 760 mmHg
Molecular Formula C12H11NO2 Melting Point 178-179 °C (dec.)(lit.)
MSDS Chinese USA Flash Point 205.0±21.8 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4-(Benzyloxy)pyridine N-oxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.1±0.1 g/cm3
Boiling Point 415.3±20.0 °C at 760 mmHg
Melting Point 178-179 °C (dec.)(lit.)
Molecular Formula C12H11NO2
Molecular Weight 201.221
Flash Point 205.0±21.8 °C
Exact Mass 201.078979
PSA 34.69000
LogP 0.59
Vapour Pressure 0.0±0.9 mmHg at 25°C
Index of Refraction 1.556

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R22;R36/37/38
Safety Phrases S26-S36-S36/37/39
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2933399090

 Synthetic Route

~88%

4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Ichihara, Yoshinori; Fujimura, Ryohei; Tsuneki, Hiroshi; Wada, Tsutomu; Okamoto, Kentaro; Gouda, Hiroaki; Hirono, Shuichi; Sugimoto, Kenji; Matsuya, Yuji; Sasaoka, Toshiyasu; Toyooka, Naoki European Journal of Medicinal Chemistry, 2013 , vol. 62, p. 649 - 660

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4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Selness, Shaun R.; Devraj, Rajesh V.; Monahan, Joseph B.; Boehm, Terri L.; Walker, John K.; Devadas, Balekudru; Durley, Richard C.; Kurumbail, Ravi; Shieh, Huey; Xing, Li; Hepperle, Michael; Rucker, Paul V.; Jerome, Kevin D.; Benson, Alan G.; Marrufo, Laura D.; Madsen, Heather M.; Hitchcock, Jeff; Owen, Tom J.; Christie, Lance; Promo, Michele A.; Hickory, Brian S.; Alvira, Edgardo; Naing, Win; Blevis-Bal, Radhika Bioorganic and Medicinal Chemistry Letters, 2009 , vol. 19, # 20 p. 5851 - 5856

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4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Shaw Journal of the American Chemical Society, 1949 , vol. 71, p. 67,69

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4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Shaw Journal of the American Chemical Society, 1949 , vol. 71, p. 67,69

~90%

4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Rodina, L. L.; Ryzhakov, A. V.; Alekseeva, O. O. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1995 , vol. 31, # 2 p. 157 - 159 Khimiya Geterotsiklicheskikh Soedinenii, 1995 , # 2 p. 184 - 186

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4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Ochiai Journal of Organic Chemistry, 1953 , vol. 18, p. 534,541 Full Text Show Details Ochiai; Teshigawara Yakugaku Zasshi, 1945 , vol. 65, # 4/8 p. 435,439 Chem.Abstr., 1951 , p. 8527

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4-(Benzyloxy)pyridine 1-oxide Structure

4-(Benzyloxy)py...

CAS#:2683-66-1

Literature: Ochiai Journal of Organic Chemistry, 1953 , vol. 18, p. 534,541

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles2

More Articles
Reactions between Grignard reagents and heterocyclic N-oxides: stereoselective synthesis of substituted pyridines, piperidines, and piperazines.

Org. Biomol. Chem. 9(2) , 337-46, (2011)

In this perspective we discuss the recent developments of stereoselective synthesis of substituted pyridines, piperidines, and piperazines from cheap and commercially readily available starting materi...

248. N-oxides and related compounds. Part X. The hydrogenation of some pyridine 1-oxides. Katritzky AR and Monro AM.

J. Chem. Soc. , 1263-66, (1958)

 Synonyms

4-(Benzyloxy)pyridine N-oxide
l^{5}-pyridin-1-one
MFCD00047427
4-benzyloxypyridine N-oxide
Pyridine,4-(benzyloxy)-,1-oxide
4-(benzyloxy)-1
4-(Benzyloxy)pyridine 1-oxide
Pyridine, 4-(phenylmethoxy)-, 1-oxide
4-benzyloxypyridine 1-oxide
pyridine N-oxide
4-Benzyloxy-pyridin-1-oxid
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