(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&
Modify Date: 2024-01-10 15:53:47
(S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI& structure
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Common Name | (S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI& | ||
|---|---|---|---|---|
| CAS Number | 274674-23-6 | Molecular Weight | 255.33000 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C17H18FN | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 145.4 °F | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | (2S)-2-[Fluoro(diphenyl)methyl]pyrrolidine |
|---|---|
| Synonym | More Synonyms |
| Molecular Formula | C17H18FN |
|---|---|
| Molecular Weight | 255.33000 |
| Exact Mass | 255.14200 |
| PSA | 12.03000 |
| LogP | 3.98050 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-36 |
| Flash Point(F) | 145.4 °F |
| Flash Point(C) | 63 °C |
|
~82%
(S)-(-)-2-(FLUO... CAS#:274674-23-6 |
| Literature: Ho, Chun-Yu; Chen, Ying-Chun; Wong, Man-Kin; Yang, Dan Journal of Organic Chemistry, 2005 , vol. 70, # 3 p. 898 - 906 |
|
~53%
(S)-(-)-2-(FLUO... CAS#:274674-23-6 |
| Literature: Sparr, Christof; Tanzer, Eva-Maria; Bachmann, Julia; Gilmour, Ryan Synthesis, 2010 , # 8 art. no. T20109SS, p. 1394 - 1397 |
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~%
(S)-(-)-2-(FLUO... CAS#:274674-23-6 |
| Literature: Ho, Chun-Yu; Chen, Ying-Chun; Wong, Man-Kin; Yang, Dan Journal of Organic Chemistry, 2005 , vol. 70, # 3 p. 898 - 906 |
![1,1-diphenyl-5,6,7,7a-tetrahydropyrrolo[1,2-c][1,3]oxazol-3-one structure](https://www.chemsrc.com/caspic/211/160424-29-3.png)
| Precursor 3 | |
|---|---|
| DownStream 0 | |
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Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.
Chemistry 36th ed., 18 , 11334-11342, (2012) The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of inter... |
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Sparr, C.; et al.
Angew. Chem. Int. Ed. Engl. 121 , 3065-3068, (2009)
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Zimmer, L. E.; et al.
Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)
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| I11-1035 |
| (S)-(-)-2-(FLUORODIPHENYLMETHYL)PYRROLI&Pyrrolidine,2-(fluorodiphenylmethyl)-,(2S) |
| (S)-2-[(fluoro)(diphenyl)methyl]pyrrolidine |
| MFCD03093547 |