5-Pyrimidinesulfonylchloride, 1,2,3,4-tetrahydro-2,4-dioxo-

Modify Date: 2024-07-18 10:24:32

5-Pyrimidinesulfonylchloride, 1,2,3,4-tetrahydro-2,4-dioxo- Structure
5-Pyrimidinesulfonylchloride, 1,2,3,4-tetrahydro-2,4-dioxo- structure
Common Name 5-Pyrimidinesulfonylchloride, 1,2,3,4-tetrahydro-2,4-dioxo-
CAS Number 28485-18-9 Molecular Weight 210.59600
Density 1.89g/cm3 Boiling Point 523.8ºC at 760mmHg
Molecular Formula C4H3ClN2O4S Melting Point N/A
MSDS N/A Flash Point 270.6ºC

 Names

Name 2,4-dioxo-1H-pyrimidine-5-sulfonyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.89g/cm3
Boiling Point 523.8ºC at 760mmHg
Molecular Formula C4H3ClN2O4S
Molecular Weight 210.59600
Flash Point 270.6ºC
Exact Mass 209.95000
PSA 108.24000
LogP 0.07150
Vapour Pressure 1.36E-11mmHg at 25°C
Index of Refraction 1.627

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 2,4-Dioxo-1,2,3,4-tetrahydropyrimidine-5-sulfonyl chloride
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H314:Causes severe skin burns and eye damage
H318:Causes serious eye damage
P260:Do not breathe dust/fume/gas/mist/vapours/spray
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P405:Store locked up

Section3. Composition/information on ingredients.
Ingredient name:2,4-Dioxo-1,2,3,4-tetrahydropyrimidine-5-sulfonyl chloride
CAS number:28485-18-9

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels, refrigerated.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Not specified
Appearance:
Boiling point:No data
Melting point:No data
Flash point:No data
Density:No data
Molecular formula:C4H3ClN2O4S
Molecular weight:210.6

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen chloride, sulfur oxides.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
UN Number:UN3261 Class: 8 Packing group: III
Proper shipping name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (2,4-Dioxo-1,2,3,4-tetrahydropyrimidine-5-
sulfonyl chloride)

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Safety Phrases 20-26-36/37/39-45-60
HS Code 2933599090

 Synthetic Route

~%

5-Pyrimidinesulfonylchloride, 1,2,3,4-tetrahydro-2,4-dioxo- Structure

5-Pyrimidinesul...

CAS#:28485-18-9

Literature: Maduskuie, Thomas P. Patent: US2003/229081 A1, 2003 ; Location in patent: Page 15 ;

 Customs

HS Code 2933599090
Summary 2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

2,4-Dioxo-1,2,3,4-tetrahydro-pyrimidin-5-sulfonylchlorid
uracil-5-sulphonyl chloride
uracil-5-sulphonic acid chloride
5-uracil-sulphonyl chloride
5-chlorosulphonyluracil
BB_SC-8836
2,4-DIBROMO-6-FLUOROPHENYL ISOTHIOCYANATE
uracil-5-sulfonyl chloride
2,4-dioxo-1,2,3,4-tetrahydro-pyrimidine-5-sulfonyl chloride