α-Chlorophenylacetyl chloride

Modify Date: 2024-01-06 10:16:45

α-Chlorophenylacetyl chloride Structure
α-Chlorophenylacetyl chloride structure
Common Name α-Chlorophenylacetyl chloride
CAS Number 2912-62-1 Molecular Weight 189.03900
Density 1.303 g/mL at 20 °C Boiling Point 120 °C23 mm Hg(lit.)
Molecular Formula C8H6Cl2O Melting Point N/A
MSDS Chinese USA Flash Point 220 °F
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger

 Names

Name 2-chloro-2-phenylacetyl chloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.303 g/mL at 20 °C
Boiling Point 120 °C23 mm Hg(lit.)
Molecular Formula C8H6Cl2O
Molecular Weight 189.03900
Flash Point 220 °F
Exact Mass 187.98000
PSA 17.07000
LogP 2.73190
Vapour Pressure 0.0753mmHg at 25°C
Index of Refraction n20/D 1.544(lit.)

 Safety Information

Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H226-H314-H335
Supplemental HS Reacts violently with water.
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C: Corrosive;
Risk Phrases R34
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 8
HS Code 2916399090

 Synthetic Route

~60%

α-Chlorophenylacetyl chloride Structure

α-Chlorophenyla...

CAS#:2912-62-1

Literature: Consortium fur elektrochemische Industrie GmbH Patent: US4639541 A1, 1987 ;

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α-Chlorophenylacetyl chloride Structure

α-Chlorophenyla...

CAS#:2912-62-1

Literature: Marzorati, Liliana; Fejfar, Jose L.; Tormena, Claudio F.; Vitta, Claudio Di Tetrahedron Asymmetry, 2012 , vol. 23, # 10 p. 748 - 753

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α-Chlorophenylacetyl chloride Structure

α-Chlorophenyla...

CAS#:2912-62-1

Literature: Altenkaemper, Mirko; Bechem, Benjamin; Perruchon, Johann; Heinrich, Swetlana; Maedel, Andrea; Ortmann, Regina; Dahse, Hans-Martin; Freunscht, Ellen; Wang, Yulin; Rath, Jennifer; Stich, August; Hitzler, Manuela; Chiba, Peter; Lanzer, Michael; Schlitzer, Martin Bioorganic and Medicinal Chemistry, 2009 , vol. 17, # 22 p. 7690 - 7697

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α-Chlorophenylacetyl chloride Structure

α-Chlorophenyla...

CAS#:2912-62-1

Literature: Schwenk; Papa Journal of the American Chemical Society, 1948 , vol. 70, p. 3626

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Detail
Literature: Gisch, John F.; Landgrebe, John A. Journal of Organic Chemistry, 1985 , vol. 50, # 12 p. 2050 - 2054

 Customs

HS Code 2916399090
Summary 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles2

More Articles
Consecutive living polymerization from cationic to radical: a straightforward yet versatile methodology for the precision synthesis of “cleavable” block copolymers with a hemiacetal ester junction. Ouchi M, et al., DOI: 10.1039/C2PY20211E

Polym. Chem. 3 , 2193-2199, (2012)

POLY (VINYLBENZYLPHOSPHONIC ACID)-BASED PROTON CONDUCTORS AS POLYMER ELECTROLYTE MEMBRANES FOR FUEL CELLS APPLICATIONS.

Polymer Prepr. 49(1) , 556, (2008)

 Synonyms

MFCD00000857
EINECS 220-826-7
a-Chlorophenylacetyl chloride
DL-2-Chloro-2-phenylacetylchloride
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