Tris(3-methoxyphenyl)phosphine

Modify Date: 2024-01-02 10:24:43

Tris(3-methoxyphenyl)phosphine Structure
Tris(3-methoxyphenyl)phosphine structure
Common Name Tris(3-methoxyphenyl)phosphine
CAS Number 29949-84-6 Molecular Weight 352.363
Density N/A Boiling Point 476.3±40.0 °C at 760 mmHg
Molecular Formula C21H21O3P Melting Point 113-115 °C(lit.)
MSDS N/A Flash Point 301.7±27.6 °C

 Names

Name tris(3-methoxyphenyl)phosphane
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 476.3±40.0 °C at 760 mmHg
Melting Point 113-115 °C(lit.)
Molecular Formula C21H21O3P
Molecular Weight 352.363
Flash Point 301.7±27.6 °C
Exact Mass 352.122833
PSA 41.28000
LogP 5.44
Vapour Pressure 0.0±1.1 mmHg at 25°C

 MSDS


Section 1: Product Identification
Chemical Name:Tris(m-methoxyphenyl)phosphine, 97+%
CAS Registry Number:29949-84-6
Formula:(m-CH3OC6H4)3P
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:Tris(3-methoxyphenyl)phosphine, Tri(m-anisyl)phosphine

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound29949-84-6100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, eyes, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
No specific information is available on the physiological effects of ingestion. May cause vomiting and diarrhea.
Ingestion:
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Fine dust may form flammable mixtures with air. Handle the material in an efficient fume hood.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white xtl.
Molecular Weight:352.37
Melting Point:115°
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture-stable solid
Hazardous Polymerization:none
Conditions to Avoid:contact with strong oxidizing agents
Incompatibility:strong oxidizing agents, halogens
Decomposition Products:carbon dioxide, carbon monoxide, phosphorus pentoxide, and organic fumes.

SECTION 11: Toxicological Information
No specific information available on this product. Related compounds have been known to affect the nervous
RTECS Data:system. Symptoms of nervous system toxicity (by oral or inhalation route) include tremors, altered reflexes,
loss of muscle coordination, limb weakness, and convulsions.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:not listed on the TSCA inventory
SARA (Title 313):not regulated by Title 313
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
WGK Germany 3
HS Code 2931900090

 Synthetic Route

~29%

Tris(3-methoxyphenyl)phosphine Structure

Tris(3-methoxyp...

CAS#:29949-84-6

Literature: Le Gall, Erwan; Ben Aissi, Karima; Lachaise, Isabelle; Troupel, Michel Synlett, 2006 , # 6 p. 954 - 956

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Tris(3-methoxyphenyl)phosphine Structure

Tris(3-methoxyp...

CAS#:29949-84-6

Literature: Journal of the Chemical Society, , p. 527,530

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Tris(3-methoxyphenyl)phosphine Structure

Tris(3-methoxyp...

CAS#:29949-84-6

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 25, p. 294 - 300

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Synonyms

P(m-OMePh)3
Tris(m-methoxyphenyl)phosphine
TRI(M-ANISYL)PHOSPHINE
Tris(m-anisyl)phosphine
Phosphine, tris(3-methoxyphenyl)-
Tris(3-methoxyphenyl)phosphine
MFCD00008386
tris(3-methoxy)phenylphosphine
tris-(3-anisyl)phosphine