4-Amino-2,2,6,6-tetramethylpiperidine

Modify Date: 2024-01-02 16:09:57

4-Amino-2,2,6,6-tetramethylpiperidine structure	Common Name	4-Amino-2,2,6,6-tetramethylpiperidine
	CAS Number	36768-62-4	Molecular Weight	156.268
	Density	0.8±0.1 g/cm3	Boiling Point	188.5±8.0 °C at 760 mmHg
	Molecular Formula	C₉H₂₀N₂	Melting Point	16-18 °C(lit.)
	MSDS	Chinese USA	Flash Point	72.2±0.0 °C
	Symbol	GHS05, GHS07	Signal Word	Danger

Name	4-Amino-2,2,6,6-tetramethylpiperidine
Synonym	More Synonyms

Density	0.8±0.1 g/cm3
Boiling Point	188.5±8.0 °C at 760 mmHg
Melting Point	16-18 °C(lit.)
Molecular Formula	C₉H₂₀N₂
Molecular Weight	156.268
Flash Point	72.2±0.0 °C
Exact Mass	156.162643
PSA	38.05000
LogP	1.60
Vapour Pressure	0.6±0.4 mmHg at 25°C
Index of Refraction	1.433
Water Solubility	soluble

4-Amino-2,2,6,6-tetramethylpiperidine MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TM4290100

CHEMICAL NAME :: Piperidine, 4-amino-2,2,6,6-tetramethyl-

CAS REGISTRY NUMBER :: 36768-62-4

BEILSTEIN REFERENCE NO. :: 0105038

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C9-H20-N2

MOLECULAR WEIGHT :: 156.31

WISWESSER LINE NOTATION :: T6NTJ B1 B1 DZ F1 F1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 906 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),53,1984

Symbol	GHS05, GHS07
Signal Word	Danger
Hazard Statements	H290-H302-H314-H412
Precautionary Statements	P273-P280-P305 + P351 + P338-P310
Personal Protective Equipment	Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xn:Harmful;
Risk Phrases	R22;R36/37/38
Safety Phrases	S26-S36/37-S45-S36/37/39
RIDADR	UN 2735 8/PG 3
WGK Germany	2
RTECS	TM4290100
Packaging Group	III
Hazard Class	8
HS Code	29333999

Precursor 8
CAS#:504-20-1 Phorone CAS#:826-36-8 2,2,6,6-tetrame... CAS#:63206-89-3 tris-2-oxypropy... CAS#:7440-48-4 Cobalt
CAS#:4168-79-0 2,2,6,6-Tetrame... CAS#:85884-12-4 (2,2,6,6-tetram... CAS#:14691-88-4 4-amino-tempo CAS#:18528-42-2 2,2,6,6,-tetram...
DownStream 10
CAS#:36410-81-8 4-isothiocyanat... CAS#:42774-15-2 N1,N3-Bis(2,2,6... CAS#:40908-37-0 4-Acetamido-2,2... CAS#:1124-69-2 2,2,6,6-Tetrame...
CAS#:1463-00-9 4-chloro-2,2,6,... CAS#:2403-88-5 2,2,6,6-Tetrame... CAS#:14691-89-5 4-Acetamido-TEM... CAS#:14691-88-4 4-amino-tempo
CAS#:72442-96-7 1-pyridin-4-yl-... CAS#:66536-36-5 3-[(2,2,6,6-tet...

HS Code	2933399090
Summary	2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Synthesis of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate and 4-acetamido-(2,2,6,6-tetramethyl-piperidin-1-yl)oxyl and their use in oxidative reactions.

Nat. Protoc. 8 , 666, (2013)

We describe the synthesis of the lesser-known stoichiometric oxidation reagent 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate (1, Bobbitt's salt), as well as of 4-acetamido-...

[Comparative characteristics of the toxicity, safety and nature of the biological effect on the body of 4-hydroxy-2,2,6,6-tetramethylpiperidine and 4-amino-2,2,6,6-tetramethylpiperidine].

Gig. Tr. Prof. Zabol. (5) , 53-4, (1984)