trimethyl(thiophen-2-yl)stannane

Modify Date: 2024-01-13 13:08:34

trimethyl(thiophen-2-yl)stannane Structure
trimethyl(thiophen-2-yl)stannane structure
 Common Name trimethyl(thiophen-2-yl)stannane
CAS Number 37496-13-2 Molecular Weight 246.93600
Density 1.4021 g/cm3 Boiling Point 91 °C(Press: 19 Torr)
Molecular Formula C7H12SSn Melting Point 301-303 °C(Solv: N，N-dimethylformamide (68-12-2))
MSDS N/A Flash Point N/A

 Names

Name trimethyl(thiophen-2-yl)stannane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4021 g/cm3
Boiling Point 91 °C(Press: 19 Torr)
Melting Point 301-303 °C(Solv: N，N-dimethylformamide (68-12-2))
Molecular Formula C7H12SSn
Molecular Weight 246.93600
Exact Mass 247.96800
PSA 28.24000
LogP 2.51840

 Synthetic Route

Thiophene(SIV) structure

Thiophene(SIV)

CAS#:188290-36-0

Trimethyltin chloride structure

Trimethyltin ch...

CAS#:1066-45-1

~71%

trimethyl(thiophen-2-yl)stannane Structure

trimethyl(thiop...

CAS#:37496-13-2

Literature: Gmelin Handbook: Sn: Org.Verb.2, 1.1.2.1.13, page 152 - 157
Trimethyltin chloride structure

Trimethyltin ch...

CAS#:1066-45-1

2-Thienylmagnesium bromide solution structure

2-Thienylmagnes...

CAS#:5713-61-1

~74%

trimethyl(thiophen-2-yl)stannane Structure

trimethyl(thiop...

CAS#:37496-13-2

Literature: Lukevits, E.; Pudova, O. A.; Popelis, Yu.; Erchak, N. P. J. Gen. Chem. USSR (Engl. Transl.), 1981 , vol. 51, # 1 p. 115 - 119,102 - 106
Bromothiophene structure

Bromothiophene

CAS#:1003-09-4

lithium,trimethyltin structure

lithium,trimethyltin

CAS#:17946-71-3

~67%

trimethyl(thiophen-2-yl)stannane Structure

trimethyl(thiop...

CAS#:37496-13-2

Literature: Kamal, Marwan R.; Al-Taweel, Samir A.; El-Abadelah, Mustafa M.; Abu Ajaj, Khalid M. Phosphorus, Sulfur, and Silicon and the Related Elements, 1997 , vol. 126, p. 65 - 74
2,5‐bis(triMethylstannyl)thiophene structure

2,5‐bis(triMeth...

CAS#:86134-26-1

~%

trimethyl(thiophen-2-yl)stannane Structure

trimethyl(thiop...

CAS#:37496-13-2

Literature: Linshoeft, Julian; Heinrich, Annika C. J.; Segler, Stephan A. W.; Gates, Paul J.; Staubitz, Anne Organic Letters, 2012 , vol. 14, # 22 p. 5644 - 5647
Isopropoxyboronic acid pinacol ester structure

Isopropoxyboron...

CAS#:61676-62-8

lithium,trimethyl(2H-thiophen-2-id-5-yl)stannane structure

lithium,trimeth...

CAS#:91509-50-1

~%

N/A structure

N/A

CAS#:1408285-51-7

trimethyl(thiophen-2-yl)stannane Structure

trimethyl(thiop...

CAS#:37496-13-2

Detail
Literature: Linshoeft, Julian; Heinrich, Annika C. J.; Segler, Stephan A. W.; Gates, Paul J.; Staubitz, Anne Organic Letters, 2012 , vol. 14, # 22 p. 5644 - 5647

 Synonyms

tributylthiophene-2-ylstannane
Stannane,trimethyl-2-thienyl
2-(trimethyltin)thiophene
2-(trimethylstannyl)thiophene
2-(tributylstannyl)thiophene
(2-thienyl)-trimethylstannane
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