(S)-(+)-Mosher's acid chloride structure
|
Common Name | (S)-(+)-Mosher's acid chloride | ||
---|---|---|---|---|
CAS Number | 39637-99-5 | Molecular Weight | 252.617 | |
Density | 1.3±0.1 g/cm3 | Boiling Point | 213.5±0.0 °C at 760 mmHg | |
Molecular Formula | C10H8ClF3O2 | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | 90.0±0.0 °C | |
Symbol |
GHS05 |
Signal Word | Danger |
Name | (R)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride |
---|---|
Synonym | More Synonyms |
Density | 1.3±0.1 g/cm3 |
---|---|
Boiling Point | 213.5±0.0 °C at 760 mmHg |
Molecular Formula | C10H8ClF3O2 |
Molecular Weight | 252.617 |
Flash Point | 90.0±0.0 °C |
Exact Mass | 252.016495 |
PSA | 26.30000 |
LogP | 5.03 |
Vapour Pressure | 0.2±0.4 mmHg at 25°C |
Index of Refraction | 1.464 |
Storage condition | −20°C |
Symbol |
GHS05 |
---|---|
Signal Word | Danger |
Hazard Statements | H314 |
Precautionary Statements | P280-P305 + P351 + P338-P310 |
Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | C |
Risk Phrases | 34 |
Safety Phrases | 26-27-36/37/39-45 |
RIDADR | UN 3265 8/PG 2 |
WGK Germany | 3 |
Packaging Group | II |
Hazard Class | 8.0 |
HS Code | 2918990090 |
HS Code | 2918990090 |
---|---|
Summary | 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0% |
High-performance liquid chromatographic resolution of enantiomers of 1-phenyl-2-aminopropanes (amphetamines) with four chiral reagents.
J. Chromatogr. A. 307 , 335, (1984) High-performance liquid chromatography (HPLC) was employed for resolution of enantiomers of chiral ring-substituted 1-phenyl-2- aminopropanes (amphetamines) and 1-phenylethylamine following derivatiza... |
|
Mosher ester analysis for the determination of absolute configuration of stereogenic (chiral) carbinol carbons.
Nat. Protoc. 2 , 2451-2458, (2007) This protocol details the most commonly used nuclear magnetic resonance (NMR)-based method for deducing the configuration of otherwise unknown stereogenic, secondary carbinol (alcohol) centers (R1R2CH... |
|
J.A. Dale, H.S. Mosher
J. Am. Chem. Soc. 95 , 512, (1973)
|
(-)-Mosher's Acid Chloride |
(-)-α-Methoxy-α-(trifluoroMethyl)phenylacetyl Chloride |
MFCD00067105 |
(S)-(+)-MTPA-Cl |
Benzeneacetyl chloride, α-methoxy-α-(trifluoromethyl)-, (αS)- |
Mosher's acid chloride |
(R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride |
(2S)-3,3,3-Trifluoro-2-methoxy-2-phenylpropanoyl chloride |
(S)-Mosher's acid chloride |
(-)-MTPA-Cl |
(2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoyl chloride |