TRICHLOROACETIC ANHYDRIDE

Modify Date: 2024-01-01 21:07:31

TRICHLOROACETIC ANHYDRIDE Structure
TRICHLOROACETIC ANHYDRIDE structure
Common Name TRICHLOROACETIC ANHYDRIDE
CAS Number 4124-31-6 Molecular Weight 308.75900
Density 1.69 g/mL at 25 °C(lit.) Boiling Point 139-141 °C60 mm Hg(lit.)
Molecular Formula C4Cl6O3 Melting Point N/A
MSDS Chinese USA Flash Point 98-100°C/11mm
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name trichloroacetic anhydride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.69 g/mL at 25 °C(lit.)
Boiling Point 139-141 °C60 mm Hg(lit.)
Molecular Formula C4Cl6O3
Molecular Weight 308.75900
Flash Point 98-100°C/11mm
Exact Mass 305.79800
PSA 43.37000
LogP 2.79660
Index of Refraction n20/D 1.484(lit.)
Stability Stable. Moisture sensitive - store under dry atmosphere. Incompatible with strong bases, strong oxidizing agents.

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H314
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C
Risk Phrases R35
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 8
HS Code 2915900090

 Synthetic Route

~60%

TRICHLOROACETIC ANHYDRIDE Structure

TRICHLOROACETIC...

CAS#:4124-31-6

Literature: Bogachev; Ulanov Russian Journal of Bioorganic Chemistry, 2003 , vol. 29, # 1 p. 56 - 65

~0%

Detail
Literature: Sinyashin, O. G.; Kostin, V. P.; Batyeva, E. S.; Pudovik, A. N.; Ivasyuk N. V. J. Gen. Chem. USSR (Engl. Transl.), 1983 , vol. 53, # 8 p. 1706 - 1713,1535 - 1541

~%

TRICHLOROACETIC ANHYDRIDE Structure

TRICHLOROACETIC...

CAS#:4124-31-6

Literature: Broekema et al. Recueil des Travaux Chimiques des Pays-Bas, 1958 , vol. 77, p. 258,262, 265

~%

TRICHLOROACETIC ANHYDRIDE Structure

TRICHLOROACETIC...

CAS#:4124-31-6

Literature: Buckney; Thomsen Chemische Berichte, 1877 , vol. 10, p. 698

~%

TRICHLOROACETIC ANHYDRIDE Structure

TRICHLOROACETIC...

CAS#:4124-31-6

Literature: Katyschkina; Kraft Zhurnal Obshchei Khimii, 1959 , vol. 29, p. 63,64,67;engl. Ausg. S. 65,66,68

~%

TRICHLOROACETIC ANHYDRIDE Structure

TRICHLOROACETIC...

CAS#:4124-31-6

Literature: Eglinton et al. Journal of the Chemical Society, 1954 , p. 1860,1864

~%

Detail
Literature: Broekema et al. Recueil des Travaux Chimiques des Pays-Bas, 1958 , vol. 77, p. 258,262, 265

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles7

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[Anhydride and halogenated-anhydride trihalogenacetic acid interaction with thymidine-5'-phosphate: ways to new activating reagents in nucleotide phosphorylation reactions].

Bioorg. Khim. 29(1) , 64-74, (2003)

The interaction of thymidine 5'-phosphate with trichloroacetic anhydride, trichloroacetyl chloride, and tribromoacetyl bromide was studied in dimethylformamide and acetonitrile in the presence of tert...

Analysis of p-chloroamphetamine and a side-chain monofluorinated analogue in rat brain.

J. Pharmacol. Methods 25(2) , 147-55, (1991)

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 Synonyms

EINECS 223-925-3
(2,2,2-trichloroacetyl) 2,2,2-trichloroacetate
Perchloroacetic Anhydride
Trichloroacetic anhydride
MFCD00000793
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