4-Fluoro-2-methylphenol

Modify Date: 2024-01-11 00:03:38

4-Fluoro-2-methylphenol Structure
4-Fluoro-2-methylphenol structure
 Common Name 4-Fluoro-2-methylphenol
CAS Number 452-72-2 Molecular Weight 126.128
Density 1.2±0.1 g/cm3 Boiling Point 198.0±20.0 °C at 760 mmHg
Molecular Formula C7H7FO Melting Point 37-38 °C(lit.)
MSDS Chinese USA Flash Point 85.0±0.0 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 4-Fluoro-2-methylphenol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 198.0±20.0 °C at 760 mmHg
Melting Point 37-38 °C(lit.)
Molecular Formula C7H7FO
Molecular Weight 126.128
Flash Point 85.0±0.0 °C
Exact Mass 126.048096
PSA 20.23000
LogP 2.23
Vapour Pressure 0.3±0.4 mmHg at 25°C
Index of Refraction 1.520

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R21/22;R36/37/38
Safety Phrases S26-S36/37/39
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
Hazard Class 4.1
HS Code 2908199090

 Synthetic Route

[2-(4-fluoro-2-methylphenoxy)ethyl]trimethylsilane structure

[2-(4-fluoro-2-...

CAS#:1338215-44-3

~80%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Dibakar, Mullick; Prakash, Anjanappa; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam Tetrahedron Letters, 2011 , vol. 52, # 41 p. 5338 - 5341
4-Bromo-o-cresol structure

4-Bromo-o-cresol

CAS#:2362-12-1

~69%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Samant, Bhupesh S.; Bhagwat, Sunil S. Applied Catalysis A: General, 2011 , vol. 394, # 1-2 p. 191 - 194
3-Fluorotoluene structure

3-Fluorotoluene

CAS#:352-70-5

~%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Nakano, Taku; Kawabata, Sally; Sugihara, Tamami; Agatsuma, Noriko; Kakuda, Hiroko; Mori, Yoshihiro Bulletin of the Chemical Society of Japan, 2003 , vol. 76, # 12 p. 2353 - 2360
4-TERT-BUTYL-2-METHYLPHENOL structure

4-TERT-BUTYL-2-...

CAS#:98-27-1

~39%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Gao, Zhanghua; Lim, Yee Hwee; Tredwell, Matthew; Li, Lei; Verhoog, Stefan; Hopkinson, Matthew; Kaluza, Wojciech; Collier, Thomas Lee; Passchier, Jan; Huiban, Mickael; Gouverneur, Veronique Angewandte Chemie - International Edition, 2012 , vol. 51, # 27 p. 6733 - 6737
p-Amino-o-cresol structure

p-Amino-o-cresol

CAS#:2835-96-3

~91%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Yoneda; Fukuhara Tetrahedron, 1996 , vol. 52, # 1 p. 23 - 36
o-cresol structure

o-cresol

CAS#:95-48-7

~44%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

2-Fluoro-6-methylphenol structure

2-Fluoro-6-meth...

CAS#:443-90-3

Literature: Misaki, Susumu Journal of Fluorine Chemistry, 1981 , vol. 17, p. 159 - 172
4-Fluoro-2-methylanisole structure

4-Fluoro-2-meth...

CAS#:399-54-2

~%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Huenig; Daum Justus Liebigs Annalen der Chemie, 1955 , vol. 595, p. 131,157
5-fluoro-2-iodotoluene structure

5-fluoro-2-iodo...

CAS#:66256-28-8

~%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Dibakar, Mullick; Prakash, Anjanappa; Selvakumar, Kumaravel; Ruckmani, Kandasamy; Sivakumar, Manickam Tetrahedron Letters, 2011 , vol. 52, # 41 p. 5338 - 5341
4-Fluoro-2-methylaniline structure

4-Fluoro-2-meth...

CAS#:452-71-1

~%

4-Fluoro-2-methylphenol Structure

4-Fluoro-2-meth...

CAS#:452-72-2

Literature: Ostaszyuski,A. et al. Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1960 , vol. 8, p. 591 - 597

 Customs

HS Code 2908199090
Summary HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

 Articles1

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 Synonyms

4-Fluor-2-methyl-phenol
4-fluoro-2-methyl-phenol
MFCD00075088
2-methyl-4-fluorophenol
Phenol, 4-fluoro-2-methyl-
4-Fluoro-2-me-phenol
4-Fluoro-2-methylphenol
QR DF B1
4-Fluoro-o-cresol
5-Fluoro-2-hydroxytoluene
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