ETHYL 1-PIPERIDINEGLYOXYLATE

Modify Date: 2024-01-08 10:18:57

ETHYL 1-PIPERIDINEGLYOXYLATE Structure
ETHYL 1-PIPERIDINEGLYOXYLATE structure
Common Name ETHYL 1-PIPERIDINEGLYOXYLATE
CAS Number 53074-96-7 Molecular Weight 185.22000
Density 1.12g/cm3 Boiling Point 261.3ºC at 760mmHg
Molecular Formula C9H15NO3 Melting Point N/A
MSDS N/A Flash Point 111.8ºC

 Names

Name ethyl 2-oxo-2-piperidin-1-ylacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.12g/cm3
Boiling Point 261.3ºC at 760mmHg
Molecular Formula C9H15NO3
Molecular Weight 185.22000
Flash Point 111.8ºC
Exact Mass 185.10500
PSA 46.61000
LogP 0.49990
Index of Refraction 1.4735-1.4755

 MSDS

Name: Ethyl 1-piperidineglyoxylate 99% Material Safety Data Sheet
Synonym:
CAS: 53074-96-7
Section 1 - Chemical Product MSDS Name:Ethyl 1-piperidineglyoxylate 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
53074-96-7 Ethyl 1-piperidineglyoxylate, 99% 99% 258-343-9
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 53074-96-7: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Clear
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 158 - 159 deg C @ 71.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0260g/cm3
Molecular Formula: C9H15NO3
Molecular Weight: 185.22

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 53074-96-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Ethyl 1-piperidineglyoxylate, 99% - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 53074-96-7: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 53074-96-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 53074-96-7 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases S26-S37-S39
HS Code 2933399090

 Synthetic Route

~69%

ETHYL 1-PIPERIDINEGLYOXYLATE Structure

ETHYL 1-PIPERID...

CAS#:53074-96-7

Literature: Enichem Anic S.p.A. Patent: US4981963 A1, 1991 ;

~99%

ETHYL 1-PIPERIDINEGLYOXYLATE Structure

ETHYL 1-PIPERID...

CAS#:53074-96-7

Literature: Gadge, Sandip T.; Bhanage, Bhalchandra M. Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6793 - 6797

~%

ETHYL 1-PIPERIDINEGLYOXYLATE Structure

ETHYL 1-PIPERID...

CAS#:53074-96-7

Literature: Wang, Jian; Morra, Nicholas A.; Zhao, Hongda; Gorman, Jeffrey S.T.; Lynch, Vincent; McDonald, Robert; Reichwein, John F.; Pagenkopf, Brian L. Canadian Journal of Chemistry, 2009 , vol. 87, # 1 SPEC. ISS. p. 328 - 334

~%

ETHYL 1-PIPERIDINEGLYOXYLATE Structure

ETHYL 1-PIPERID...

CAS#:53074-96-7

Literature: Ungnade; Kissinger Journal of Organic Chemistry, 1959 , vol. 24, p. 666

~%

ETHYL 1-PIPERIDINEGLYOXYLATE Structure

ETHYL 1-PIPERID...

CAS#:53074-96-7

Literature: Wallach; Lehmann Justus Liebigs Annalen der Chemie, 1887 , vol. 237, p. 241,243

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

ethyl 2-oxo-2-piperidylacetate
Ethyl 1-piperidineglyoxylate
MFCD00006485
ethyl piperidine glyoxalate
1w8m
EINECS 258-343-9
oxo-piperidin-1-yl-acetic acid ethyl ester
E1P
oxo-piperidino-acetic acid ethyl ester
Oxo-piperidino-essigsaeure-aethylester
Ethyl 1-piperidineoxoacetate
ETHYL OXO(PIPERIDIN-1-YL)ACETATE
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