ETHYL 1-PIPERIDINEGLYOXYLATE structure
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Common Name | ETHYL 1-PIPERIDINEGLYOXYLATE | ||
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CAS Number | 53074-96-7 | Molecular Weight | 185.22000 | |
Density | 1.12g/cm3 | Boiling Point | 261.3ºC at 760mmHg | |
Molecular Formula | C9H15NO3 | Melting Point | N/A | |
MSDS | N/A | Flash Point | 111.8ºC |
Name | ethyl 2-oxo-2-piperidin-1-ylacetate |
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Synonym | More Synonyms |
Density | 1.12g/cm3 |
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Boiling Point | 261.3ºC at 760mmHg |
Molecular Formula | C9H15NO3 |
Molecular Weight | 185.22000 |
Flash Point | 111.8ºC |
Exact Mass | 185.10500 |
PSA | 46.61000 |
LogP | 0.49990 |
Index of Refraction | 1.4735-1.4755 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. Ingestion: The toxicological properties of this substance have not been fully investigated. Inhalation: Causes respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Exposure Limits CAS# 53074-96-7: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 158 - 159 deg C @ 71.00mm Hg Freezing/Melting Point: Not available. Autoignition Temperature: Not available. Flash Point: > 112 deg C (> 233.60 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: 1.0260g/cm3 Molecular Formula: C9H15NO3 Molecular Weight: 185.22 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 53074-96-7 unlisted. LD50/LC50: Not available. Carcinogenicity: Ethyl 1-piperidineglyoxylate, 99% - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 53074-96-7: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 53074-96-7 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 53074-96-7 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi |
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Risk Phrases | R36/37/38 |
Safety Phrases | S26-S37-S39 |
HS Code | 2933399090 |
~69% ETHYL 1-PIPERID... CAS#:53074-96-7 |
Literature: Enichem Anic S.p.A. Patent: US4981963 A1, 1991 ; |
~99% ETHYL 1-PIPERID... CAS#:53074-96-7 |
Literature: Gadge, Sandip T.; Bhanage, Bhalchandra M. Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6793 - 6797 |
~% ETHYL 1-PIPERID... CAS#:53074-96-7 |
Literature: Wang, Jian; Morra, Nicholas A.; Zhao, Hongda; Gorman, Jeffrey S.T.; Lynch, Vincent; McDonald, Robert; Reichwein, John F.; Pagenkopf, Brian L. Canadian Journal of Chemistry, 2009 , vol. 87, # 1 SPEC. ISS. p. 328 - 334 |
~% ETHYL 1-PIPERID... CAS#:53074-96-7 |
Literature: Ungnade; Kissinger Journal of Organic Chemistry, 1959 , vol. 24, p. 666 |
~% ETHYL 1-PIPERID... CAS#:53074-96-7 |
Literature: Wallach; Lehmann Justus Liebigs Annalen der Chemie, 1887 , vol. 237, p. 241,243 |
Precursor 7 | |
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DownStream 3 | |
HS Code | 2933399090 |
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Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
ethyl 2-oxo-2-piperidylacetate |
Ethyl 1-piperidineglyoxylate |
MFCD00006485 |
ethyl piperidine glyoxalate |
1w8m |
EINECS 258-343-9 |
oxo-piperidin-1-yl-acetic acid ethyl ester |
E1P |
oxo-piperidino-acetic acid ethyl ester |
Oxo-piperidino-essigsaeure-aethylester |
Ethyl 1-piperidineoxoacetate |
ETHYL OXO(PIPERIDIN-1-YL)ACETATE |