Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate structure
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Common Name | Tris[triphenylphosphinegold(I)]oxonium tetrafluoroborate | ||
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CAS Number | 53317-87-6 | Molecular Weight | 1480.56000 | |
Density | N/A | Boiling Point | N/A | |
Molecular Formula | C54H45Au3BF4OP3 | Melting Point | 207ºC (dec.) | |
MSDS | Chinese USA | Flash Point | N/A | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | oxidanium,gold,triphenylphosphane,tetrafluoroborate |
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Synonym | More Synonyms |
Melting Point | 207ºC (dec.) |
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Molecular Formula | C54H45Au3BF4OP3 |
Molecular Weight | 1480.56000 |
Exact Mass | 1480.17000 |
PSA | 50.00000 |
LogP | 11.55850 |
Storage condition | 2-8°C |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xi |
Risk Phrases | 36/37/38 |
Safety Phrases | 26-36/37/39 |
RIDADR | NONH for all modes of transport |
~% Tris[triphenylp... CAS#:53317-87-6 |
Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1991 , p. 783 - 788 |
~0% Tris[triphenylp... CAS#:53317-87-6
Detail
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Literature: Grohmann, Andreas; Riede, Juergen; Schmidbaur, Hubert Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1992 , vol. 47, # 9 p. 1255 - 1260 |
~14% Tris[triphenylp... CAS#:53317-87-6 |
Literature: Banditelli, Guido; Bandini, Anna Laura; Bonati, Flavio; Goel, Ram G.; Minghetti, Giovanni Gazzetta Chimica Italiana, 1982 , vol. 112, p. 539 - 542 |
~% Tris[triphenylp... CAS#:53317-87-6 |
Literature: Cinellu, Maria Agostina; Stoccoru, Sergio; Minghetti, Giovanni; Bandini, Anna Laura; Demartin, Francesco Inorganica Chimica Acta, 1990 , vol. 168, p. 33 - 42 |
Gold(I)-catalyzed propargyl Claisen rearrangement.
J. Am. Chem. Soc. 126 , 15978, (2004) Homoallenic alcohols are prepared from propargyl vinyl ethers using a trinuclear gold(I)-oxo complex, [(Ph3PAu)3O]BF4, as a catalyst for propargyl Claisen rearrangement at room temperature. The gold(I... |
tris[(triphenylphosphane)gold(I)]oxonium tetrafluoroborate |
tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate |
MFCD06658141 |
[(PPh3Au)3O]BF4 |
[(Ph3PAu)3O]BF4 |
TRIS[TRIPHENYLPHOSPHINEGOLD(I)]OXONIUM TETRAFLUOROBORATE |
Oxotris(triphenylphosphine)trigold tetrafluoroborate |
Oxotris((triphenylphosphine)gold) tetrafluoroborate |
[Au(PPh3)O]BF4 |
{[(triphenylphosphino)Au]3O}BF4 |
Tris(triphenylphosphinegold)oxonium tetrafluoroborate |