(phenylselenomethyl)trimethylsilane structure
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Common Name | (phenylselenomethyl)trimethylsilane | ||
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CAS Number | 56253-60-2 | Molecular Weight | 243.28000 | |
Density | 1.176 g/mL at 25ºC(lit.) | Boiling Point | 106ºC6 mm Hg(lit.) | |
Molecular Formula | C10H16SeSi | Melting Point | N/A | |
MSDS | N/A | Flash Point | >230 °F |
Name | trimethyl(phenylselanylmethyl)silane |
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Synonym | More Synonyms |
Density | 1.176 g/mL at 25ºC(lit.) |
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Boiling Point | 106ºC6 mm Hg(lit.) |
Molecular Formula | C10H16SeSi |
Molecular Weight | 243.28000 |
Flash Point | >230 °F |
Exact Mass | 244.01900 |
LogP | 2.31180 |
Index of Refraction | n20/D 1.552(lit.) |
Version 1.2
Regulation (EC) No 1907/2006 1 - Product and Company Information Product Name(PHENYLSELENOMETHYL)TRIMETHYLSILANE, 99% 2 - Hazards Identification SPECIAL INDICATION OF HAZARDS TO HUMANS AND THE ENVIRONMENT Toxic by inhalation and if swallowed. Danger of cumulative
effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3 - Composition/Information on Ingredients Product NameCAS #EC noAnnex I Index Number (PHENYLSELENOMETHYL)TRIMETHYLSILAN 56253-60-2 260-077-3 034-002-00-8 E FormulaC10H16SeSi Molecular Weight 243,2900 AMU 4 - First Aid Measures AFTER INHALATION If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. AFTER SKIN CONTACT In case of contact, immediately wash skin with soap and copious amounts of water. AFTER EYE CONTACT In case of contact, immediately flush eyes with copious amounts of water for at least 15 minutes. AFTER INGESTION If swallowed, wash out mouth with water provided person is conscious. Call a physician. 5 - Fire Fighting Measures ALDRICHwww.molbase.com EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. SPECIAL RISKS Specific Hazard(s): Emits toxic fumes under fire conditions. SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. 6 - Accidental Release Measures PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear respirator, chemical safety goggles, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Cover with dry lime or soda ash, pick up, keep in a closed container, and hold for waste disposal. Ventilate area and wash spill site after material pickup is complete. 7 - Handling and Storage HANDLING Directions for Safe Handling: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. STORAGE Conditions of Storage: Keep tightly closed. Store in a cool dry place. 8 - Exposure Controls / Personal Protection ENGINEERING CONTROLS Safety shower and eye bath. Mechanical exhaust required. GENERAL HYGIENE MEASURES Wash thoroughly after handling. Wash contaminated clothing before reuse. PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection: Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Hand Protection: Compatible chemical-resistant gloves. Eye Protection: Chemical safety goggles. 9 - Physical and Chemical Properties AppearanceColor: Deep yellow-green Form: Clear liquid PropertyValueAt Temperature or Pressure ALDRICHwww.molbase.com pH N/A BP/BP Range106,000 °C6,000 mmHg MP/MP RangeN/A Flash Point95,000 °CMethod: closed cup FlammabilityN/A Autoignition TempN/A Oxidizing Properties N/A Explosive Properties N/A Explosion LimitsN/A Vapor PressureN/A SG/Density1,1760 g/cm3 Partition Coefficient N/A ViscosityN/A Vapor DensityN/A Saturated Vapor Conc. N/A Evaporation RateN/A Bulk DensityN/A Decomposition Temp.N/A Solvent ContentN/A Water ContentN/A Surface TensionN/A ConductivityN/A Miscellaneous DataN/A SolubilityN/A 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide, Silicon oxide, Selenium/selenium oxides. 11 - Toxicological Information SIGNS AND SYMPTOMS OF EXPOSURE To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. ROUTE OF EXPOSURE Multiple Routes: May be harmful by inhalation, ingestion, or skin absorption. May cause irritation. TARGET ORGAN INFORMATION Liver. 12 - Ecological Information No data available. 13 - Disposal Considerations SUBSTANCE DISPOSAL Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. 14 - Transport Information ALDRICHwww.molbase.com RID/ADR UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. IMDG UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. Marine Pollutant: No Severe Marine Pollutant: No Technical Name: Required IATA UN#: 2810 Class: 6.1 PG: III Proper Shipping Name: Toxic liquid, organic, n.o.s. Inhalation Packing Group I: No Technical Name: Required 15 - Regulatory Information CLASSIFICATION AND LABELING ACCORDING TO EU DIRECTIVES ANNEX I INDEX NUMBER: 034-002-00-8 NOTA: A INDICATION OF DANGER: T-N Toxic. Dangerous for the environment. R-PHRASES: 23/25-33-50/53 Toxic by inhalation and if swallowed. Danger of cumulative effects. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-PHRASES: 20/21-28-45-60-61 When using do not eat, drink, or smoke. After contact with skin, wash immediately with plenty of soap-suds. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. COUNTRY SPECIFIC INFORMATION Germany WGK: 3 Self-Classification 16 - Other Information WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Inc., shall not be held liable for any damage resulting from handling or ALDRICHwww.molbase.com from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2010 Co. License granted to make unlimitedpaper copies for internal use only. DISCLAIMER For R&D use only. Not for drug, household or other uses. ALDRICHwww.molbase.com SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | T,N |
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Risk Phrases | 23/25-33-50/53 |
Safety Phrases | 20/21-28-45-60-61 |
RIDADR | UN 2810 6.1/PG 3 |
WGK Germany | 3 |
Packaging Group | III |
Hazard Class | 6.1(b) |
~54% (phenylselenome... CAS#:56253-60-2 |
Literature: Yamamoto, Terahisa; Moriura, Eri; Sawa, Arisa; Yoshimatsu, Mitsuhiro Chemistry Letters, 2008 , vol. 37, # 10 p. 1046 - 1047 |
~36% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 30, # 25 p. 3333 - 3334 |
~% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4103 - 4106 |
~% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4103 - 4106 |
~% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4103 - 4106 |
~% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4103 - 4106 |
~% (phenylselenome... CAS#:56253-60-2 |
Literature: Tetrahedron Letters, , vol. 23, # 40 p. 4103 - 4106 |
Phenylselenomethyltrimethylsilan |
Phenylselenotrimethylsilylmethane |
Trimethyl(phenylselenomethyl)silane |
(Phenylselenomethyl)trimethylsilane |
EINECS 260-077-3 |
MFCD00042834 |