n-(4-fluorobenzylidene)aniline

Modify Date: 2024-01-04 10:54:23

n-(4-fluorobenzylidene)aniline Structure
n-(4-fluorobenzylidene)aniline structure
Common Name n-(4-fluorobenzylidene)aniline
CAS Number 5676-81-3 Molecular Weight 199.22400
Density 1.035g/cm3 Boiling Point 296.169ºC at 760 mmHg
Molecular Formula C13H10FN Melting Point 40-44ºC
MSDS N/A Flash Point 132.919ºC

 Names

Name n-(4-fluorobenzylidene)aniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.035g/cm3
Boiling Point 296.169ºC at 760 mmHg
Melting Point 40-44ºC
Molecular Formula C13H10FN
Molecular Weight 199.22400
Flash Point 132.919ºC
Exact Mass 199.08000
PSA 12.36000
LogP 3.57630
Index of Refraction 1.539

 MSDS

Name: N-(4-Fluorobenzylidene)aniline 98% Material Safety Data Sheet
Synonym:
CAS: 5676-81-3
Section 1 - Chemical Product MSDS Name:N-(4-Fluorobenzylidene)aniline 98% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5676-81-3 N-(4-Fluorobenzylidene)aniline 98% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5676-81-3: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C13H10FN
Molecular Weight: 199.23

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5676-81-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
N-(4-Fluorobenzylidene)aniline - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 5676-81-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5676-81-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5676-81-3 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn,Xi
Risk Phrases R20/21/22
Safety Phrases S36/37
HS Code 2925290090

 Synthetic Route

~80%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Chen, Jing; Huang, Shijun; Lin, Jin; Su, Weiping Applied Catalysis A: General, 2014 , vol. 470, p. 1 - 7

~64%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Zhang, Erlei; Tian, Haiwen; Xu, Sendong; Yu, Xiaochun; Xu, Qing Organic Letters, 2013 , vol. 15, # 11 p. 2704 - 2707

~76%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Simion, Alina; Simion, Cristian; Kanda, Tadeshige; Nagashima, Satoko; Mitoma, Yoshiharu; Yamada, Tomoko; Mimura, Keisuke; Tashiro, Masashi Journal of the Chemical Society. Perkin Transactions 1, 2001 , # 17 p. 2071 - 2078

~18%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: RSC Advances, , vol. 4, # 6 p. 2596 - 2600

~77%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Sivasubramanian, S.; Ramamoorthy, V.; Balasubramanian, G. Organic Preparations and Procedures International, 1995 , vol. 27, # 2 p. 221 - 224

~91%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Mitchell, Laura; Gonzalez-Santiago, Berenice; Mowat, John P. S.; Gunn, Mary E.; Williamson, Patrick; Acerbi, Nadia; Clarke, Matthew L.; Wright, Paul A. Catalysis Science and Technology, 2013 , vol. 3, # 3 p. 606 - 617

~%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Synlett, , # 11 p. 1565 - 1568

~%

n-(4-fluorobenzylidene)aniline Structure

n-(4-fluorobenz...

CAS#:5676-81-3

Literature: Synlett, , # 11 p. 1565 - 1568

 Customs

HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Synonyms

4-fluorobenzalaniline
MFCD00017971
4-FLUOROBENZYLIDENEANILINE
4-Fluorbenzylidenanilin
4-fluorobenzaldehyde phenylimine
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