bis(i-propylcyclopentadienyl)nickel

Synonym:Bis(1-methylethylcyclopentadienyl)nickel (II)

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound57197-55-4100%0.2mg/m3 (as Ni)1mg/m3 (as Ni)

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Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and mucous membranes. Nickel and certain nickel compounds may cause cancer.
Primary Routes of Exposure:Ingestion, eyes
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to vomiting, and diarrhea.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects. May cause cancer.
NTP:Yes
IARC:Yes
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Highly flammable. Formation of explosive air/vapor mixtures is possible.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be absorbed into vermiculite or other chemical adsorbent and swept up.

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SECTION 7: Handling and Storage
Store cold. Keep area away from heat and direct sunlight. This product may degrade on contact with air.
Handling and Storage:
Store under an inert atmosphere of nitrogen or argon.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:green liquid
Molecular Weight:273.04
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

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SECTION 10: Stability and Reactivity
Stability:air sensitive (store cold)
Hazardous Polymerization:none
Conditions to Avoid:contact with strong oxidizing agents
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and nickel oxide.

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SECTION 11: Toxicological Information
RTECS Data:No information available in RTECS.
Carcinogenic Effects:Nickel and certain nickel compounds are anticipated to be carcinogens.
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Flammable liquids, N.O.S.
Hazard Class (CFR):3
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN #1993
Shipping Name (IATA):Flammable liquid, N.O.S.
Hazard Class (IATA):3
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1993

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SECTION 15: Regulatory Information
TSCA:not listed on the TSCA inventory
SARA (Title 313):See Category Code N495 for reporting.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A