brommethylacetat

Modify Date: 2024-01-08 09:26:40

brommethylacetat Structure
brommethylacetat structure
Common Name brommethylacetat
CAS Number 590-97-6 Molecular Weight 152.975
Density 1.6±0.1 g/cm3 Boiling Point 132.7±23.0 °C at 760 mmHg
Molecular Formula C3H5BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 57.2±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name Bromomethyl Acetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 132.7±23.0 °C at 760 mmHg
Molecular Formula C3H5BrO2
Molecular Weight 152.975
Flash Point 57.2±0.0 °C
Exact Mass 151.947281
PSA 26.30000
LogP 0.87
Vapour Pressure 8.8±0.2 mmHg at 25°C
Index of Refraction 1.450
Storage condition Hygroscopic, -20?C Freezer, Under Inert Atmosphere

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR UN 3272 3/PG 3
WGK Germany 3
Packaging Group III
Hazard Class 3.2

 Synthetic Route

~38%

brommethylacetat Structure

brommethylacetat

CAS#:590-97-6

Literature: Daiitchi Radioisotope Laboratories, Ltd. Patent: US6239145 B1, 2001 ;

~70%

brommethylacetat Structure

brommethylacetat

CAS#:590-97-6

Literature: Benneche, Tore; Strande, Per; Wiggen, Unni Acta Chemica Scandinavica, 1989 , vol. 43, # 1 p. 74 - 77

~83%

brommethylacetat Structure

brommethylacetat

CAS#:590-97-6

Literature: Grynkiewicz, Grzegorz; Tsien, Roger Y. Polish Journal of Chemistry, 1987 , vol. 61, # 4-6 p. 443 - 447

~%

brommethylacetat Structure

brommethylacetat

CAS#:590-97-6

Literature: Chem. Zentralbl., , vol. 71, # I p. 1122

~75%

brommethylacetat Structure

brommethylacetat

CAS#:590-97-6

Literature: Sosnovsky, George; Rao, Nuti Uma Maheswara; Li, Shu Wen; Swartz, Harold M. Journal of Organic Chemistry, 1989 , vol. 54, # 15 p. 3667 - 3674

 Articles3

More Articles
O6-alkylguanine-DNA alkyltransferase has opposing effects in modulating the genotoxicity of dibromomethane and bromomethyl acetate.

Chem. Res. Toxicol. 17(6) , 742-52, (2004)

O(6)-Alkylguanine-DNA alkyltransferase (AGT) is a DNA repair protein that removes O(6)-alkylguanine adducts. The interaction of dibromomethane (CH(2)Br(2)) and bromomethyl acetate (BrCH(2)OAc) with AG...

Optically active cyclohexene derivative as a new antisepsis agent: an efficient synthesis of ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate (TAK-242).

Chem. Pharm. Bull. 54(1) , 58-62, (2006)

Two new synthetic methods were established for the efficient synthesis of optically active cyclohexene antisepsis agent, ethyl (6R)-6-[N-(2-chloro-4-fluorophenyl)sulfamoyl]cyclohex-1-ene-1-carboxylate...

A direct preparation of 1, 2-diacetates from aldehydes and ketones promoted by samarium diiodide. Enholm EJ and Satici H.

Tetrahedron Lett. 32(22) , 2433-36, (1991)

 Synonyms

MFCD00000170
Bromomethanol acetate
Methanol, 1-bromo-, acetate
Methanol, bromo-, acetate
brommethylacetat
EINECS 209-696-2
Bromomethyl acetate
BROMO METHYL ACETATE