3-chloro-p-cresol

Modify Date: 2024-01-11 11:06:11

3-chloro-p-cresol Structure
3-chloro-p-cresol structure
Common Name 3-chloro-p-cresol
CAS Number 615-62-3 Molecular Weight 142.583
Density 1.2±0.1 g/cm3 Boiling Point 228.0±0.0 °C at 760 mmHg
Molecular Formula C7H7ClO Melting Point 55 °C
MSDS Chinese USA Flash Point 88.5±21.8 °C
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name 3-chloro-4-methylphenol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 228.0±0.0 °C at 760 mmHg
Melting Point 55 °C
Molecular Formula C7H7ClO
Molecular Weight 142.583
Flash Point 88.5±21.8 °C
Exact Mass 142.018539
PSA 20.23000
LogP 2.86
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.566

 MSDS


Section1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product name: 3-Chloro-4-methylphenol

Section2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
According to Regulation (EC) No1272/2008
Acute toxicity, Inhalation (Category 4)
Acute toxicity, Dermal (Category 4)
Acute toxicity, Oral (Category 4)
Skin irritation (Category 2)
Serious eye damage (Category 1)
Specific target organ toxicity - single exposure (Category 3)
According to European Directive 67/548/EEC as amended.
Harmful by inhalation, in contact with skin and if swallowed. Irritating to respiratory system and skin. Risk of
serious damage to eyes.
Label elements
Pictogram
Signal wordDanger
Hazard statement(s)
H302Harmful if swallowed.
H312Harmful in contact with skin.
H315Causes skin irritation.
H318Causes serious eye damage.
H332Harmful if inhaled.
H335May cause respiratory irritation.
Precautionary statement(s)
P261Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P280Wear protective gloves/ eye protection/ face protection.
P305 + P351 + P338IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Hazard symbol(s)
XnHarmful
R-phrase(s)
R20/21/22Harmful by inhalation, in contact with skin and if swallowed.
R37/38Irritating to respiratory system and skin.
R41Risk of serious damage to eyes.
S-phrase(s)
S26In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S39Wear eye/face protection.
Other hazards - none

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Formula: C7H7ClO
Molecular Weight: 142,58 g/mol
CAS-No.EC-No.Index-No.ClassificationConcentration
3-Chloro-p-cresol
615-62-3210-439-1-Acute Tox. 4; Skin Irrit. 2; Eye-
Dam. 1; STOT SE 3; H302,
H312, H315, H318, H332,
H335
Xn, R20/21/22 - R37/38 - R41
For the full text of the H-Statements mentioned in this Section, see Section 16.

Section4. FIRST AID MEASURES
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
Environmental precautions
Do not let product enter drains.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire
protection.
Conditions for safe storage
Keep container tightly closed in a dry and well-ventilated place. Store in cool place.

Section8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle respirator
type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the
respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and
components tested and approved under appropriate government standards such as NIOSH (US) or CEN
(EU).
Hand protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without
touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves
after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Eye protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
Complete suit protecting against chemicals, The type of protective equipment must be selected according
to the concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Formsolid
Safety data
pH no data available
Melting point48 - 53 °C
Boiling point228 °C at 1.013 hPa
Flash pointno data available
Ignition temperature no data available
Lower explosion limit no data available
Upper explosion limit no data available
Water solubilityno data available
Partition coefficient: log Pow: 2,778
n-octanol/water

Section10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Conditions to avoid
no data available
Materials to avoid
Oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas

Section11. TOXICOLOGICAL INFORMATION
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
InhalationHarmful if inhaled. Causes respiratory tract irritation.
IngestionHarmful if swallowed.
SkinHarmful if absorbed through skin. Causes skin irritation.
Eyes
Causes eye burns.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.
Additional Information
RTECS: Not available

Section12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available

Section13. DISPOSAL CONSIDERATIONS
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Contact a licensed professional
waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent
and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

Section14. TRANSPORT INFORMATION
ADR/RID
Not dangerous goods
IMDG
Not dangerous goods
IATA
Not dangerous goods

Section15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

Section16. OTHER INFORMATION
Text of H-code(s) and R-phrase(s) mentioned in Section 3
Acute Tox.Acute toxicity
Eye Dam.Serious eye damage
H302Harmful if swallowed.
H312Harmful in contact with skin.
H315Causes skin irritation.
H318Causes serious eye damage.
H332Harmful if inhaled.
H335May cause respiratory irritation.
Skin Irrit.Skin irritation
STOT SESpecific target organ toxicity - single exposure
XnHarmful
R20/21/22Harmful by inhalation, in contact with skin and if swallowed.
R37/38Irritating to respiratory system and skin.
R41Risk of serious damage to eyes.
Further information
Copyright 2010 Co. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and is
applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee
of the properties of the product. Co., shall not be held liable for any damage resulting from
handling or from contact with the above product. See reverse side of invoice or packing slip for additional
terms and conditions of sale.

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302-H312-H315-H318-H332-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes C,T,Xi,Xn
Risk Phrases R20/21/22
Safety Phrases S23-S36/37/39
RIDADR 3437
Packaging Group II
Hazard Class 6.1
HS Code 2908199090

 Synthetic Route

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3-chloro-p-cresol Structure

3-chloro-p-cresol

CAS#:615-62-3

Literature: DE156333 ;

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3-chloro-p-cresol Structure

3-chloro-p-cresol

CAS#:615-62-3

Literature: Tetrahedron, , vol. 39, # 1 p. 193 - 198

~%

3-chloro-p-cresol Structure

3-chloro-p-cresol

CAS#:615-62-3

Literature: Canadian Journal of Chemistry, , vol. 65, p. 1233 - 1240

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3-chloro-p-cresol Structure

3-chloro-p-cresol

CAS#:615-62-3

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 51, p. 98,109

 Customs

HS Code 2908199090
Summary HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

 Synonyms

3-chloro-4-methyl-phenol
3-Chlor-4-methyl-phenol
3-Chloro-4-methylphenol
p-Cresol,3-chloro
p-Cresol, 3-chloro-
3-Chlor-p-kresol
3-chloro-p-cresol
2-chloro-4-hydroxytoluene
MFCD00060319
Phenol, 3-chloro-4-methyl-
EINECS 210-439-1
Phenol,3-chloro-4-methyl
2-Chlor-4-hydroxy-toluol
2-Chlor-4-oxy-1-methyl-benzol
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