Methyl 3-bromobenzoate

Modify Date: 2024-01-04 18:20:54

Methyl 3-bromobenzoate Structure
Methyl 3-bromobenzoate structure
 Common Name Methyl 3-bromobenzoate
CAS Number 618-89-3 Molecular Weight 215.044
Density 1.5±0.1 g/cm3 Boiling Point 244.4±13.0 °C at 760 mmHg
Molecular Formula C8H7BrO2 Melting Point 31-33 °C(lit.)
MSDS USA Flash Point 101.6±19.8 °C

 Names

Name Methyl 3-bromobenzoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 244.4±13.0 °C at 760 mmHg
Melting Point 31-33 °C(lit.)
Molecular Formula C8H7BrO2
Molecular Weight 215.044
Flash Point 101.6±19.8 °C
Exact Mass 213.962936
PSA 26.30000
LogP 2.88
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.550
Storage condition Room temperature.

 MSDS

Methyl 3-Bromobenzoate Revision number: 1
SAFETY DATA SHEET
Section1. BASE INFORMATION
Product name:Methyl 3-Bromobenzoate

Revision number:1
Section2. HAZARDS IDENTIFICATION
Classification of the GHS
PHYSICAL HAZARDSNot classified
HEALTH HAZARDSNot classified
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements
None
Pictograms or hazard symbols
Signal wordNo signal word
None
Hazard statement
Precautionary statementsNone
Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Component(s):Methyl 3-Bromobenzoate
Percent:>99.0%(GC)
CAS Number:618-89-3
Synonyms:3-Bromobenzoic Acid Methyl Ester
Chemical Formula:C8H7BrO2
Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact:Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.
Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards:Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
Methyl 3-Bromobenzoate
Section5. FIRE-FIGHTING MEASURES
Specific methods:Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:
Section6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.
Section7. HANDLING AND STORAGE
Handling
Handling is performed in a well ventilated place. Wear suitable protective equipment.
Technical measures:
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling:Avoid contact with skin, eyes and clothing.
Storage
Storage conditions:Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material:Law is followed.
Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Hand protection:Protective gloves.
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.
Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:crystal
Color:White - Pale yellow
Odor:No data available
pH: No data available
Melting point/freezing point:30°C (Freezing point)
Boiling Point/Range:No data available
Flash Point:No data available
Explosive limits
Lower:No data available
Upper:No data available
Density:No data available
Solubility:No data available
Section10. STABILITY AND REACTIVITY
Stability:Stable under proper conditions.
Reactivity:No special reactivity has been reported.
Incompartible materials: oxidizing agents
Methyl 3-Bromobenzoate
Section10. STABILITY AND REACTIVITY
Hazardous Decomposition Carbon monoxide, Carbon dioxide, Hydrogen bromide
Products:
Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC =No data available
NTP =No data available
Reproductive toxicity:No data available
Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
No data available
Fish:
Crustacea:No data available
No data available
Algae:
Persistence / degradability: No data available
No data available
Bioaccumulative
potential(BCF):
Mobillity in soil
log Pow:No data available
No data available
Soil adsorption (Koc):
Henry's LawNo data available
constant(PaM3/mol):
Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.
Section14. TRANSPORT INFORMATION
Hazards Class:Does not correspond to the classification standard of the United Nations
Not Listed
UN-No:
Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26,
2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
prescribed.
Methyl 3-Bromobenzoate

SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S37/39-S26
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2916399090

 Synthetic Route

 Customs

HS Code 2916399090
Summary 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles3

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 Synonyms

3-methoxycarbonyl-1-bromobenzene
(3-bromophenyl)acetic acid methyl ester
m-bromobenzoic acid methyl ester
Methyl 3-bromobenzoate
Benzoic acid, m-bromo-, methyl ester
MFCD00017777
Benzoic acid,3-bromo-,methyl ester
Methyl-3-brombenzolcarboxylat
Benzoic acid, 3-bromo-, methyl ester
methyl-3-bromobenzoate
Methyl m-bromobenzoate
EINECS 210-569-9
3-MeO2CC6H4Br
3-Bromobenzoic acid,methyl ester
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